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  • The half-wave potentials, E1/2, of twenty four polynitro arenes have been determined in aqueous medium buffered at pH 7, the final concentrations of their solutions being 0.5x10?4 M and 0.5x10?5 M. The found logical relationships between the E1/2 values and squares of detonation velocity are of the type of the modified Evans?Polanyi?Semenov equation for energetic materials. It has been stated that the strong dependence of E1/2 values on the conditions and way of realisation of the polarographic measurements considerably restrict the application of this method to studies of micro-mechanism of initiation of organic energetic materials.
  • The half-wave potentials, E1/2, of twenty four polynitro arenes have been determined in aqueous medium buffered at pH 7, the final concentrations of their solutions being 0.5x10?4 M and 0.5x10?5 M. The found logical relationships between the E1/2 values and squares of detonation velocity are of the type of the modified Evans?Polanyi?Semenov equation for energetic materials. It has been stated that the strong dependence of E1/2 values on the conditions and way of realisation of the polarographic measurements considerably restrict the application of this method to studies of micro-mechanism of initiation of organic energetic materials. (en)
  • Půlvlnný potenciál dvaceti čtyři polynitro arenes byl stanovený ve vodných prostředích pufrovaných na pH 7, pro dvě koncentrace. Nalezené logické vztahy mezi těmito potenciály a čtverci detonačních rychlosti jsou jedním z forem modifikované Evans?Polanyi?Semenovovy rovnice pro energetické materiály. Silná závislost hodnoty potenciálů na podmínkách a způsobu polarografických měření značně omezujr použití polarografie ve studiu mikro-mechanismu uvedení organických materiálů (cs)
Title
  • Polarography in the Study of Chemical Micro-Mechanism of Initiation of Polynitro Arenes
  • Polarography in the Study of Chemical Micro-Mechanism of Initiation of Polynitro Arenes (en)
  • Polarografie ve studiu chenického mikro-mechanizmu iniciace polynitroarenů (cs)
skos:prefLabel
  • Polarography in the Study of Chemical Micro-Mechanism of Initiation of Polynitro Arenes
  • Polarography in the Study of Chemical Micro-Mechanism of Initiation of Polynitro Arenes (en)
  • Polarografie ve studiu chenického mikro-mechanizmu iniciace polynitroarenů (cs)
skos:notation
  • RIV/00216275:25310/04:00003527!RIV08-MSM-25310___
http://linked.open.../vavai/riv/strany
  • 171-179
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • S
http://linked.open...iv/cisloPeriodika
  • 22
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 580082
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/04:00003527
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Polarography; Chemical Micro-Mechanism of Initiation; Polynitro Arenes (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [A570F14CB677]
http://linked.open...i/riv/nazevZdroje
  • Journal of Energetic Materials
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • N
http://linked.open...iv/tvurceVysledku
  • Zeman, Svatopluk
  • Zemanová, Eva
issn
  • 0737-0652
number of pages
http://localhost/t...ganizacniJednotka
  • 25310
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