About: Electrochemical and spectrometric study of FOX-7 in aprotic solvents

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	2,2-Dinitroethene-1,1-diamine (FOX-7) is a recently developed and broadly tested energetic material with high efficiency and low sensitivity. Generally, explosion is based on thermally initiated chain of intramolecular redox reactions. Recently it has been found that electrochemical reduction in aqueous solutions is also able to provoke the chain of follow-up processes leading to total decomposition of the parent substance yielding gaseous products analogously like during explosion. Similarly, results from reductive electrolysis of FOX-7 in aprotic solvents show analogous course of degradation. The first transferred electron activates the molecule and initiated the formation of colored radical intermediates that have been spectroscopically characterized 2,2-Dinitroethene-1,1-diamine (FOX-7) is a recently developed and broadly tested energetic material with high efficiency and low sensitivity. Generally, explosion is based on thermally initiated chain of intramolecular redox reactions. Recently it has been found that electrochemical reduction in aqueous solutions is also able to provoke the chain of follow-up processes leading to total decomposition of the parent substance yielding gaseous products analogously like during explosion. Similarly, results from reductive electrolysis of FOX-7 in aprotic solvents show analogous course of degradation. The first transferred electron activates the molecule and initiated the formation of colored radical intermediates that have been spectroscopically characterized (en)
Title	Electrochemical and spectrometric study of FOX-7 in aprotic solvents Electrochemical and spectrometric study of FOX-7 in aprotic solvents (en)
skos:prefLabel	Electrochemical and spectrometric study of FOX-7 in aprotic solvents Electrochemical and spectrometric study of FOX-7 in aprotic solvents (en)
skos:notation	RIV/61388955:_____/11:00361543!RIV12-AV0-61388955
http://linked.open...avai/predkladatel	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(ME09002), Z(AV0Z40400503)
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Klíma, Jiří Šimková, Ludmila Ludvík, Jiří
http://linked.open.../riv/druhVysledku	D - Článek ve sborníku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	197020
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/11:00361543
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	electrolysis; polarography; FOX-7 (en)
http://linked.open.../riv/klicoveSlovo	polarography FOX-7 electrolysis
http://linked.open...ontrolniKodProRIV	[82E5F32C4F8B]
http://linked.open...v/mistoKonaniAkce	Jetřichovice
http://linked.open...i/riv/mistoVydani	Ústí nad Labem
http://linked.open...i/riv/nazevZdroje	Sborník přednášek. XXXI. Moderní elektrochemické metody
http://linked.open...in/vavai/riv/obor	CG
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	Chemical and Electrochemical Properties of Aromatic Dialdehydes and their Derivatives, Chemical Principles of Sensors for Aminoacids and New Disinfection Processes
http://linked.open...UplatneniVysledku	2011
http://linked.open...iv/tvurceVysledku	Klíma, Jiří Ludvík, Jiří Šimková, Ludmila
http://linked.open...vavai/riv/typAkce	WRD - Světová
http://linked.open.../riv/zahajeniAkce	2011-05-23 (xsd:date)
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace
number of pages	4 (xsd:int)
http://purl.org/ne...btex#hasPublisher	BEST servis
https://schema.org/isbn	978-80-254-9634-3
is http://linked.open...avai/riv/vysledek of	Electrochemical and spectrometric study of FOX-7 in aprotic solvents Electrochemical and spectrometric study of FOX-7 in aprotic solvents

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