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Description
| - The goals of this project are 1) Elucidation of mechanisms of complex reactions of orthophthalaldehyde (OPA) with amino acids and other nucleophiles. This serves for optimalization of biochemical analyses based on rational development of reliable, fast and well-reproducible procedures for determination of amino acids. 2) Contribution to the understanding of interactions of OPA and its derivatives with primary amino groups and thiolate anions of some peptides to establish chemical principles of biocide activity of OPA. This will allow development of optimum conditions for new type of disinfection applications. 3) Elucidation of the role of intramolecular interaction of two carbonyl or azomethine groups and their position on an aromatic benzenoid ring to demonstrate, how such interaction is reflected by their oxidation-reduction and acido-basic properties, spectra and reactivity. This will enable a formulation of mere general rules, based on correlation of electrochemical data with other physic (en)
- Navržení a chemické zdůvodnění - spolehlivého a reprodukovatelného stanovení aminokyselin - optimálních podmínek pro desinfekci pomocí OPA za pokojové teploty Získání obecně využitelných poznatků o vztahu struktura-reaktivita u aromatických dialdehydů
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Title
| - Chemical and Electrochemical Properties of Aromatic Dialdehydes and their Derivatives, Chemical Principles of Sensors for Aminoacids and New Disinfection Processes (en)
- Chemické a elektrochemické vlastnosti aromatických dialdehydů a jejich derivátů, chemický princip senzorů na aminokyseliny a nových desinfekčních postupů
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skos:notation
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http://linked.open...avai/cep/aktivita
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http://linked.open...kovaStatniPodpora
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http://linked.open...ep/celkoveNaklady
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http://linked.open...datumDodatniDoRIV
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http://linked.open...i/cep/druhSouteze
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http://linked.open...ep/duvernostUdaju
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http://linked.open.../cep/fazeProjektu
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http://linked.open...ai/cep/hlavniObor
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http://linked.open...hodnoceniProjektu
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http://linked.open...vai/cep/kategorie
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http://linked.open.../cep/klicovaSlova
| - aromatic dialdehydes; orthophthalaldehyde; oximes; imines; molecules with two redox centers; polarography; voltammetry; electrochemistry; spectrophotometry; quantum chemical calculations; electroanalysis; determination of amino acids (en)
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http://linked.open...ep/partnetrHlavni
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http://linked.open...inujicichPrijemcu
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http://linked.open...cep/pocetPrijemcu
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http://linked.open...ocetSpoluPrijemcu
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http://linked.open.../pocetVysledkuRIV
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http://linked.open...enychVysledkuVRIV
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http://linked.open...lneniVMinulemRoce
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http://linked.open.../prideleniPodpory
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http://linked.open...iciPoslednihoRoku
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http://linked.open...atUdajeProjZameru
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http://linked.open.../vavai/cep/soutez
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http://linked.open...usZobrazovaneFaze
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http://linked.open...ai/cep/typPojektu
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http://linked.open...ep/ukonceniReseni
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http://linked.open.../cep/vedlejsiObor
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http://linked.open...ep/zahajeniReseni
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http://linked.open...jektu+dodavatelem
| - Kinetics and equilibria in biologically significant reaction of o-phthalaldehyde with ammonia, amines and thiols, aminoacids and oligopeptides were investigated electrochemically and spectrometrically. As model compounds for intramolecular interactions substituted calixarenes, carboranes and nitroolephines were used. Characterized and corresponding mechanisms were formulated. (en)
- Elektrochemicky a spektrometricky byla prostudována kinetika a rovnováhy při biologicky významné reakci o-ftalaldehydu s amoniakem, aminy a thioly, s aminokyselinami a s oligopeptidy. Jako modelové látky pro intramolekulární interakce sloužily substituované kalixareny, karborany a nitroolefiny. Některé produkty byly izolovány a charakterizovány a byly formulovány příslušné mechanismy. (cs)
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http://linked.open...tniCyklusProjektu
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http://linked.open.../cep/klicoveSlovo
| - electroanalysis
- electrochemistry
- polarography
- voltammetry
- imines
- molecules with two redox centers
- orthophthalaldehyde
- oximes
- quantum chemical calculations
- spectrophotometry
- aromatic dialdehydes
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is http://linked.open...vavai/riv/projekt
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is http://linked.open...vavai/cep/projekt
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