About: SBA-15 Immobilized Ruthenium Carbenes as Catalysts for Ring Closing Metathesis and Ring Opening Metathesis Polymerization

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	New hybrid catalysts for olefin metathesis were prepared by immobilization of Hoveyda-Grubbs type Ru alkylidenes on a siliceous SBA-15 support via exchange of chloro ligands for substituted carboxylates. Catalysts proved a high activity in ring closing metathesis of 1,7-octadiene and diethyl diallylmalonate, reusability and low Ru leaching. In Ring Opening Metathesis Polymerization of norbornene and cyclooctene, SBA-15 supported catalyst gave higher yields of high-molecular-weight polymers than corresponding catalyst with conventional silica support. New hybrid catalysts for olefin metathesis were prepared by immobilization of Hoveyda-Grubbs type Ru alkylidenes on a siliceous SBA-15 support via exchange of chloro ligands for substituted carboxylates. Catalysts proved a high activity in ring closing metathesis of 1,7-octadiene and diethyl diallylmalonate, reusability and low Ru leaching. In Ring Opening Metathesis Polymerization of norbornene and cyclooctene, SBA-15 supported catalyst gave higher yields of high-molecular-weight polymers than corresponding catalyst with conventional silica support. (en)
Title	SBA-15 Immobilized Ruthenium Carbenes as Catalysts for Ring Closing Metathesis and Ring Opening Metathesis Polymerization SBA-15 Immobilized Ruthenium Carbenes as Catalysts for Ring Closing Metathesis and Ring Opening Metathesis Polymerization (en)
skos:prefLabel	SBA-15 Immobilized Ruthenium Carbenes as Catalysts for Ring Closing Metathesis and Ring Opening Metathesis Polymerization SBA-15 Immobilized Ruthenium Carbenes as Catalysts for Ring Closing Metathesis and Ring Opening Metathesis Polymerization (en)
skos:notation	RIV/61388955:_____/10:00341739!RIV11-AV0-61388955
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GD203/08/H032), P(IAA400400805), P(KAN100400701), Z(AV0Z40400503), Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika	3-4
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Dědeček, Jiří Balcar, Hynek Bek, David Žilková, Naděžda
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	286395
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/10:00341739
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	ring closing metathesis; ring opening metathesis polymerization; hybrid catalysts (en)
http://linked.open.../riv/klicoveSlovo	ring opening metathesis polymerization hybrid catalysts ring closing metathesis
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[04FCE46AE4D6]
http://linked.open...i/riv/nazevZdroje	Topics in Catalysis
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Advanced immobilized metathesis catalysts for fine chemical synthesis Hybride nanocomposite materials Advanced catalytic processes and materials
http://linked.open...UplatneniVysledku	2010
http://linked.open...v/svazekPeriodika	53
http://linked.open...iv/tvurceVysledku	Dědeček, Jiří Sedláček, J. Balcar, Hynek Bek, David Žilková, Naděžda
http://linked.open...ain/vavai/riv/wos	000275558000009
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí
issn	1022-5528
number of pages	10 (xsd:int)
is http://linked.open...avai/riv/vysledek of	SBA-15 Immobilized Ruthenium Carbenes as Catalysts for Ring Closing Metathesis and Ring Opening Metathesis Polymerization SBA-15 Immobilized Ruthenium Carbenes as Catalysts for Ring Closing Metathesis and Ring Opening Metathesis Polymerization SBA-15 Immobilized Ruthenium Carbenes as Catalysts for Ring Closing Metathesis and Ring Opening Metathesis Polymerization

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