About: Iron magnesium-bearing beryl from granitic pegmatites: an EMPA, LA-ICP-MS, Mössbauer spectroscopy, and powder XRD study     Goto   Sponge   Distinct   Permalink

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  • Five samples of blue, bluish green, and green Fe,Mg-enriched beryl from Li-poor granitic pegmatites [beryl-columbite (LCT) pegmatites at Kovářová and Boněnov in the Czech Republic and Val Sissone in Italy; a primitive pegmatite at Beryller, Untersulzbachtal, Austria; and a euxenite (NYF) pegmatite from the Beryl Pit, Quadeville, Ontario) were investigated using EMPA, Mössbauer spectroscopy, LA-ICP-MS, and powder XRD diffraction. The EMPA data show highly heterogeneous (Kovářová, Val Sissone) to rather homogeneous crystals (Boněnov, Beryller, Quadeville), with high variations in Al (1.51-1.91 apfu), Mg (0.01-0.31), Fetot (0.01-0.18), and Na (0.04-0.37). The substitution CH? + OR3+ ? CHR+ + OR2+ is dominant and supported by the powder XRD data. LA-ICP-MS revealed notable concentrations of some trace elements: Cs ? 7568 ppm (Kovářová), Li ? 928 ppm (Quadeville), Sc ? 2823 ppm (Val Sissone). Beryl samples have mostly comparable contents of Fe3+, ~ 25% at the O-site, but differ in the presence of Fe2+ at the T(2)-site. Primitive characteristics of some examined beryl (Mg/(Mg+Fetot) = 0.37-0.68 reflect low degree of fractionation of the host pegmatite (Beryller), or high degree of Mg-contamination from host metabasites in the pegmatite dikes (Kovářová, Boněnov). The concentrations and ratios of selected elements including Fe3+/Fe2+ in beryl from these Li-poor pegmatites are not feasible for any implications of pegmatite-family affinity or degree of its fractionation except for Li; however, no evident correlation between Li and Cs contents was found.
  • Five samples of blue, bluish green, and green Fe,Mg-enriched beryl from Li-poor granitic pegmatites [beryl-columbite (LCT) pegmatites at Kovářová and Boněnov in the Czech Republic and Val Sissone in Italy; a primitive pegmatite at Beryller, Untersulzbachtal, Austria; and a euxenite (NYF) pegmatite from the Beryl Pit, Quadeville, Ontario) were investigated using EMPA, Mössbauer spectroscopy, LA-ICP-MS, and powder XRD diffraction. The EMPA data show highly heterogeneous (Kovářová, Val Sissone) to rather homogeneous crystals (Boněnov, Beryller, Quadeville), with high variations in Al (1.51-1.91 apfu), Mg (0.01-0.31), Fetot (0.01-0.18), and Na (0.04-0.37). The substitution CH? + OR3+ ? CHR+ + OR2+ is dominant and supported by the powder XRD data. LA-ICP-MS revealed notable concentrations of some trace elements: Cs ? 7568 ppm (Kovářová), Li ? 928 ppm (Quadeville), Sc ? 2823 ppm (Val Sissone). Beryl samples have mostly comparable contents of Fe3+, ~ 25% at the O-site, but differ in the presence of Fe2+ at the T(2)-site. Primitive characteristics of some examined beryl (Mg/(Mg+Fetot) = 0.37-0.68 reflect low degree of fractionation of the host pegmatite (Beryller), or high degree of Mg-contamination from host metabasites in the pegmatite dikes (Kovářová, Boněnov). The concentrations and ratios of selected elements including Fe3+/Fe2+ in beryl from these Li-poor pegmatites are not feasible for any implications of pegmatite-family affinity or degree of its fractionation except for Li; however, no evident correlation between Li and Cs contents was found. (en)
Title
  • Iron magnesium-bearing beryl from granitic pegmatites: an EMPA, LA-ICP-MS, Mössbauer spectroscopy, and powder XRD study
  • Iron magnesium-bearing beryl from granitic pegmatites: an EMPA, LA-ICP-MS, Mössbauer spectroscopy, and powder XRD study (en)
skos:prefLabel
  • Iron magnesium-bearing beryl from granitic pegmatites: an EMPA, LA-ICP-MS, Mössbauer spectroscopy, and powder XRD study
  • Iron magnesium-bearing beryl from granitic pegmatites: an EMPA, LA-ICP-MS, Mössbauer spectroscopy, and powder XRD study (en)
skos:notation
  • RIV/61989592:15310/14:33152315!RIV15-MSM-15310___
http://linked.open...avai/riv/aktivita
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  • P(ED2.1.00/03.0058), P(GAP210/10/0743)
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  • 2
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  • 22857
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  • RIV/61989592:15310/14:33152315
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  • beryl, iron, magnesium, EMPA, LA-ICP-MS, Mössbauer spectroscopy, granitic pegmatites (en)
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  • CA - Kanada
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  • [C01201CD37DD]
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  • Canadian Mineralogist
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  • 52
http://linked.open...iv/tvurceVysledku
  • Filip, Jan
  • Gadas, Petr
  • Novák, Milan
  • Přikryl, Jan
  • Vašinová Galiová, Michaela
issn
  • 0008-4476
number of pages
http://bibframe.org/vocab/doi
  • 10.3749/canmin.52.2.271
http://localhost/t...ganizacniJednotka
  • 15310
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