About: Spin crossover behavior of a one-dimensional polymeric-chain compound {[Fe(abpt)2(u-Ni(CN)4)].xH2O}n (x = 0.5 -0): Synthesis, spectral, thermal and magnetic properties

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About: Spin crossover behavior of a one-dimensional polymeric-chain compound {[Fe(abpt)2(u-Ni(CN)4)].xH2O}n (x = 0.5 -0): Synthesis, spectral, thermal and magnetic properties Goto Sponge Distinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	A one-dimensional polymeric-chain iron(II)-nickel(II) cyanido-bridged complex of the composition{[Fe(abpt)2(u-Ni(CN)4)].0.5H2O}n (1.0.5H2O), where abpt = 4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole, was prepared and characterized by elemental and thermal analyses, FTIR and 57Fe Mössbauer spectroscopies,and magnetic measurements. The incomplete spin crossover phenomenon was observed with approximately 12% of the frozen high-spin fraction at low temperatures and with the spin transition critical temperature above room temperature. A one-dimensional polymeric-chain iron(II)-nickel(II) cyanido-bridged complex of the composition{[Fe(abpt)2(u-Ni(CN)4)].0.5H2O}n (1.0.5H2O), where abpt = 4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole, was prepared and characterized by elemental and thermal analyses, FTIR and 57Fe Mössbauer spectroscopies,and magnetic measurements. The incomplete spin crossover phenomenon was observed with approximately 12% of the frozen high-spin fraction at low temperatures and with the spin transition critical temperature above room temperature. (en)
Title	Spin crossover behavior of a one-dimensional polymeric-chain compound {[Fe(abpt)2(u-Ni(CN)4)].xH2O}n (x = 0.5 -0): Synthesis, spectral, thermal and magnetic properties Spin crossover behavior of a one-dimensional polymeric-chain compound {[Fe(abpt)2(u-Ni(CN)4)].xH2O}n (x = 0.5 -0): Synthesis, spectral, thermal and magnetic properties (en)
skos:prefLabel	Spin crossover behavior of a one-dimensional polymeric-chain compound {[Fe(abpt)2(u-Ni(CN)4)].xH2O}n (x = 0.5 -0): Synthesis, spectral, thermal and magnetic properties Spin crossover behavior of a one-dimensional polymeric-chain compound {[Fe(abpt)2(u-Ni(CN)4)].xH2O}n (x = 0.5 -0): Synthesis, spectral, thermal and magnetic properties (en)
skos:notation	RIV/61989592:15310/11:10222341!RIV12-MSM-15310___
http://linked.open...avai/predkladatel	Přírodovědecká fakulta
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GP203/09/P370), P(KAN115600801), Z(MSM6198959218)
http://linked.open...iv/cisloPeriodika	1
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Zbořil, Radek Trávníček, Zdeněk Herchel, Radovan
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Palackého v Olomouci / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	231440
http://linked.open...ai/riv/idVysledku	RIV/61989592:15310/11:10222341
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Iron(II) complex, Polycyanidometallates, Spin crossover, Spin transition (en)
http://linked.open.../riv/klicoveSlovo	Iron(II) complex Polycyanidometallates Spin crossover Spin transition
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[55F3CEB757D5]
http://linked.open...i/riv/nazevZdroje	Inorganica Chimica Acta
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	New technologies of preparation and exploitation of iron oxide-based nanoparticles for environmental, industrial and medical applications Molecular magnetism based on transition metal complexes
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	365
http://linked.open...iv/tvurceVysledku	Herchel, Radovan Trávníček, Zdeněk Zbořil, Radek
http://linked.open...ain/vavai/riv/wos	000285624200068
http://linked.open...n/vavai/riv/zamer	Komplexní sloučeniny a oxidy přechodných kovů s využitím v bioaplikacích a nanotechnologiích
issn	0020-1693
number of pages	4 (xsd:int)
http://localhost/t...ganizacniJednotka	15310
is http://linked.open...avai/riv/vysledek of	Spin crossover behavior of a one-dimensional polymeric-chain compound {[Fe(abpt)2(u-Ni(CN)4)].xH2O}n (x = 0.5 -0): Synthesis, spectral, thermal and magnetic properties Spin crossover behavior of a one-dimensional polymeric-chain compound {[Fe(abpt)2(u-Ni(CN)4)].xH2O}n (x = 0.5 -0): Synthesis, spectral, thermal and magnetic properties

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