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  • Si-rich zeolites are the widest group of catalysts used in industrial processes. One of the key parameters which control properties of Si-rich zeolites is Al siting in the individual framework T sites. Significant progress in determining Al distribution in Si-rich matrices was achieved by the application of 27Al MQ MAS NMR combined with quantum mechanical calculations [1,2]. However, the presence of Al-O-(Si-O)2-Al sequences in these materials significantly affects both Al geometry and NMR parameters [3]. A new general approach therefore is needed to investigate the Al siting in Si-rich zeolite frameworks containing both isolated Al atoms and Al-O-(Si-P-O)n-Al (n = 1,2) sequences.
  • Si-rich zeolites are the widest group of catalysts used in industrial processes. One of the key parameters which control properties of Si-rich zeolites is Al siting in the individual framework T sites. Significant progress in determining Al distribution in Si-rich matrices was achieved by the application of 27Al MQ MAS NMR combined with quantum mechanical calculations [1,2]. However, the presence of Al-O-(Si-O)2-Al sequences in these materials significantly affects both Al geometry and NMR parameters [3]. A new general approach therefore is needed to investigate the Al siting in Si-rich zeolite frameworks containing both isolated Al atoms and Al-O-(Si-P-O)n-Al (n = 1,2) sequences. (en)
Title
  • Analysis of the Aluminum Siting in the Framework of Silicon-Rich Zeolites. A Multispectroscopic Approach
  • Analysis of the Aluminum Siting in the Framework of Silicon-Rich Zeolites. A Multispectroscopic Approach (en)
skos:prefLabel
  • Analysis of the Aluminum Siting in the Framework of Silicon-Rich Zeolites. A Multispectroscopic Approach
  • Analysis of the Aluminum Siting in the Framework of Silicon-Rich Zeolites. A Multispectroscopic Approach (en)
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  • RIV/61388955:_____/11:00371892!RIV12-AV0-61388955
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  • P(IAA400400812), P(IAA400400904), P(IAA400400908), P(KAN100400702), Z(AV0Z40400503)
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  • 185775
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  • RIV/61388955:_____/11:00371892
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  • aluminum siting; ferrierite; UV-Vis spectroscopy (en)
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  • [E17D53F6FC9B]
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  • Napoli
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  • Proceedings of the 10th Congress of Italian Zeolite Association. Advances in Zeolite Science and Technology. An International Symposium celebrating Carmine Colella´s 70th birthday
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  • Dědeček, Jiří
  • Gao, Fei
  • Klein, Petr
  • Li, Chengbin
  • Lucero, Melissa Jeanine
  • Sklenák, Štěpán
  • Tvarůžková, Zdenka
  • Urbanová, Martina
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  • De Frede Editore
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  • 978-88-89976-33-3
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