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| Description
| - In accordance with priorities of the Sub-programme 1 the goals of the project are: a) to develop synthetic methods for preparation of novel nanostructured and nanocomposite materials, which will utilize unique properties of nanoparticles made of metals (alloys), oxides (mixed oxides) and their interactions with inorganic substrates; b) to obtain deep understanding of the functioning of these materials in catalytic, electrocatalytic and sorption processes, and c) to extend the scope of industrial technologies in the material production in the CR via transfer of acquired know-how. Prepared nano-materials will be tailored for the use in environmentally friendly applications in the field of fuels, energy sources and pollutant removal, particularly for catalytic transformation of n-alkanes to iso-alkanes; electrocatalytic oxidation of aliphatic alcohols in fuel cells; and sorption based removal of radionuclides of Cs, Sr, Eu and Am from radioactive wastes of low activity. (en)
- Ve shodě s prioritami Podprogramu 1 je cílem tohoto projektu (a) vypracovat metody přípravy nových nanostrukturních a nanokompozitních materiálů založených na unikátních vlastnostech nanočástic (slitin) kovů a (směsných) oxidů kovů a jejich interakci s anorganickými nosiči, (b)získat systematické údaje týkající se principu fungování těchto materiálů v katalytických, elektrokatalytických a sorpčních aplikacích, a (c) transferem poznatků rozšířit spektrum průmyslově využitelných technologií v materiálové výrobě v ČR. Tyto materiály budou cíleně strukturovány pro environmentálně přijatelné chemické technologie zasahující do oblasti paliv, energetických zdrojů a odstraňování polutantů; zejména však pro katalytickou transformaci n-alkanů na iso-alkany; elektrokatalytickou oxidaci alifatických alkoholů v palivových článcích; sorpční procesy pro odstraňování radionuklidů s dlouhým poločasem rozpadu (Cs, Sr, Eu, Am) ze středně a nízkoaktivních jaderných odpadů.
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| Title
| - Nanostructured materials for catalytic, electrocatalytic and sorption applications (en)
- Nanostrukturní materiály pro katalytické, elektrokatalytické a sorpční aplikace
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| skos:notation
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| http://linked.open...avai/cep/aktivita
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| http://linked.open...kovaStatniPodpora
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| http://linked.open...ep/celkoveNaklady
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| http://linked.open...datumDodatniDoRIV
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| http://linked.open...i/cep/druhSouteze
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| http://linked.open...ep/duvernostUdaju
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| http://linked.open.../cep/fazeProjektu
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| http://linked.open...ai/cep/hlavniObor
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| http://linked.open...hodnoceniProjektu
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| http://linked.open...vai/cep/kategorie
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| http://linked.open.../cep/klicovaSlova
| - nanostructured materials; catalysis; electrocatalysis; sorption; metals; metal oxides; chemical technology (en)
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| http://linked.open...ep/partnetrHlavni
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| http://linked.open...inujicichPrijemcu
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| http://linked.open...cep/pocetPrijemcu
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| http://linked.open...ocetSpoluPrijemcu
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| http://linked.open.../pocetVysledkuRIV
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| http://linked.open...enychVysledkuVRIV
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| http://linked.open...lneniVMinulemRoce
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| http://linked.open.../prideleniPodpory
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| http://linked.open...iciPoslednihoRoku
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| http://linked.open...atUdajeProjZameru
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| http://linked.open.../vavai/cep/soutez
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| http://linked.open...usZobrazovaneFaze
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| http://linked.open...ai/cep/typPojektu
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| http://linked.open...ep/ukonceniReseni
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| http://linked.open.../cep/vedlejsiObor
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| http://linked.open...ep/zahajeniReseni
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| http://linked.open...jektu+dodavatelem
| - Methods for preparation of nanostructured catalysts ZrO2/WOx, FeOx and CoOx in zeolites, Ru-Co-O, WO3, Pt-CeOx and SnO2 doped by Pt or Pd, and monodimensional ZnO have been developed. Prepared FeOx and TiOx nanosorbents for capture of radionuclides. (en)
- Byly vypracovány metody přípravy nanostrukturních katalyzátorů ZrO2/WOx, FeOx a CoOx v zeolitech, Ru-Co-O, WO3, Pt-CeOx a SnO2 dopovaných Pt a Pd, a monodimensionální ZnO. Připraveny nanosorbenty na bázi oxidů Fe a Ti pro záchyt radionuklidů. (cs)
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| http://linked.open...tniCyklusProjektu
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| http://linked.open.../cep/klicoveSlovo
| - nanostructured materials
- catalysis
- electrocatalysis
- metal oxides
- metals
- sorption
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| is http://linked.open...vavai/riv/projekt
of | - Technická zpráva : Pokročilé materiály druhé generace pro separaci Eu s TODGA a nanomateriály Elmarco
- Technical report : Study of sorbent capacities and various Ti and Fe oxides
- Photoemission spectroscopy study of Cu/CeO2 systems: Cu/CeO2 nanosized catalyst and CeO2(111) / Cu(111) inverse model catalyst
- Effect of Al-Si-Al and Al-Si-Si-Al Pairs in the ZSM-5 Zeolite Framework on the Al-27 NMR Spectra. A Combined High-Resolution Al-27 NMR and DFT/MM Study
- Effect of Al/Si Substitutions and Silanol Nests on the Local Geometry of Si and Al Framework Sites in Silicone-Rich Zeolites: A Combined High Resolution Al-27 and Si-29 NMR and Density Functional Theory/Molecular Mechanics Study
- Carborane-thiol-silver interactions. A comparative study of the molecular protection of silver surfaces
- Au and Au3 ions in CeO2 rf-sputtered thin films (Art. No. 115301)
- Anode Material for Hydrogen Polymer Membrane Fuel Cell: Pt-CeO2 RF-Sputtered Thin Films
- Electron delocalization in vinyl ruthenium substituted cyclophanes: Assessment of the through-space and the through-bond pathways
- Geopolymer based catalysts-New group of catalytic materials
- Nano project: 2011 technical report, NRI Rez
- Reversible Intramolecular Single-Electron Oxidative Addition Involving a Hemilabile Noninnocent Ligand
- Carboranedithiols: Building Blocks for Self-Assembled Monolayers on Copper Surfaces
- Spectroelectrochemistry and DFT Analysis of a New {RuNO}n Redox System with Multifrequency EPR Suggesting Conformational Isomerism in the {RuNO}7 State
- Způsob výroby zeolitů pentasilové struktury s řízenou distribucí hliníkových atomů ve skeletu
- Technická zpráva : Studium prvotních materiálů LiTi a Fe oxidy
- Control of metal ion species in zeolites by distribution of aluminium in the framework: From structural analysis to performance under real conditions of SCR-NOx and NO, N2O decomposition
- Complex Analysis of the Aluminum Siting in the Framework of Silicon-Rich Zeolites. A Case Study on Ferrierites
- Tailoring of Fe-ferrierite for N2O decomposition: On the decisive role of framework Al distribution for catalytic activity of Fe species in Fe-ferrierite
- Vinyl-ruthenium entities as markers for intramolecular electron transfer processes
- Summary technnical report (2007-2011) NRI Rez
- Decaborane Thiols as Building Blocks for Self-Assembled Monolayers on Metal Surfaces
- Electrochemical design of ZnO hierarchical structures for dye-sensitized solar cells
- Siting and Distribution of Framework Aluminium Atoms in Silicon-Rich Zeolites and Impact on Catalysis
- A facile synthesis of mesoporous crystalline tin oxide films involving a base-triggered formation of sol–gel building blocks
- Analysis of the Aluminum Siting in the Framework of Silicon-Rich Zeolites. A Multispectroscopic Approach
- Effect of the particle size and surface area of tungstated zirconia on the WOx nuclearity and n-heptane isomerization over Pt/WO3–ZrO2
- FTIR in situ mechanistic study of the NH3-NO/NO2 %22Fast SCR%22 reaction over a commercial Fe-ZSM-5 catalyst
- Charge transport in DNA oligonucleotides with various base-pairing patterns
- Parallel oxygen and chlorine evolution on Ru1-xNixO2-y nanostructured electrodes
- Redox Properties of Ruthenium Nitrosyl Porphyrin Complexes with Different Axial Ligation: Structural, Spectroelectrochemical (IR, UV-VIS, EPR) and Theoretical Studies
- Influence of oxygen on reactivity of Ru1-xFexO2-y – doped materials
- Singlet Diradical Complexes of Ruthenium and Osmium: Geometrical and Electronic Structures and their Unexpected Changes on Oxidation
- Nanosecond CO Photodissociation and Excited-State Character of [Ru(X)(X´)(CO)2(N,N´-diisopropyl-1,4-diazabutadiene)] (X = X´ = Cl or I; X = Me, X´ = I; X = SnPh3, X´ = Cl) Studied by Time-Resolved Infrared Spectroscopy and DFT Calculations
- Effect of aluminium distribution in the framework of ZSM-5 on hydrocarbon transformation. Cracking of 1-butene
- A tetranuclear organorhenium(I) complex of the 2,3,5,6-tetrafluoro-7,7,8,8-tetracyano-p-quinodimethane radical anion, TCNQF4.-
- Stabilizing the Elusive ortho-Quinone/Copper(I) Oxidation State Combination through .pi./.pi. Interaction in an Isolated Complex
- Halide Ligands-More Than Just sigma-Donors? A Structural and Spectroscopic Study of Homologous Organonickel Complexes
- Silver(I), Copper(I) and Copper(II) Complex of the New N,Se-Chelate Ligand 2-Phenylselenomethyl-1H-benzimidazole: Electrochemistry and Structure
- An Odd-Electron Complex [Ru-k(NOm)(Q(n))(terpy)](2+) with Two Prototypical Non-Innocent Ligands
- Behavior of Active Oxygen During the Decomposition of Nitrous Oxide Over Fe-FER
- XPS study of early stages of Al/Au interface formation
- Oxygen evolution on nanocrystalline RuO2 and Ru0.9Ni0.1O2δ electrodes – DEMS approach to reaction mechanism determination
- A Five-Center Redox System: Molecular Coupling of Two Noninnocent Imino-o-benzoquinonato-Ruthenium Functions through a .pi. Acceptor Bridge
- Effect of metal exchange (Os vs Ru) and co-ligand variation (Cl- vs acac-) on the oxidation state distribution in complexes of an o-phenylenediamido(2-)/o-quinonediimine redox system
- Charge Delocalization in a Heterobimetallic Ferrocene-(Vinyl)Ru(CO)Cl(PiPr3)2 System
- Evidence for the dimer-of-(mixed-valent dimers) configuration in tetranuclear {(mu(4)-TCNX)[Ru(NH3)(5)](4)}(8+), TCNX = TCNE and TCNQ, from DFT calculations
- Electron Transfer Across Multiple Hydrogen Bonds: The Case of Ureapyrimidinedione-Substituted Vinyl Ruthenium and Osmium Complexes
- Boron Atoms as Spin Carriers in Two- and Three-Dimensional Systems
- The Semiquinone-Ruthenium Combination as a Remarkably Invariant Feature in the Redox and Substitution Series [Ru(Q)(n)(acac)(3-n)](m), n=1-3; m = (-2),-1, 0,+1, (+2); Q=4,6-Di-tert-butyl-N-phenyl-o-iminobenzoquinone
- 2-Organoselenomethyl-1H-benzimidazole Complexes of Copper(II) and Copper(I)
- Ligand-Centred Reactivity of Bis(picolyl)amine Iridium: Sequential Deprotonation, Oxidation and Oxygenation of a %22Non-Innocent%22 Ligand
- Oxygen evolution on Ru1-xNixO2-y nanocrystalline electrodes
- Mesoporous molecular sieves based catalysts for olefin metathesis and metathesis polymerization
- The 1,4-diazabutadiene/1,2-enediamido non-innocent ligand system in the formation of iridaheteroaromatic compounds: Spectroelectrochemistry and electronic structure
- Fluorescent nanodiamonds: effect of surface termination
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