About: Control of metal ion species in zeolites by distribution of aluminium in the framework: From structural analysis to performance under real conditions of SCR-NOx and NO, N2O decomposition

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The structure, properties and activity of the counter Co, Cu and Fe ion species depending on the distribution of aluminium atoms in the framework between Al pairs of Al-O-(Si-O)(2)-Al sequences in one ring and isolated Al atoms (Al-O-(Si-O)(n>2)-Al sequences) in two rings are analyzed. The effect of the Al distribution on the activity of metal ion species is investigated for reactions of technology importance, i.e. SCR-NOx by propane, and decomposition of NO and N2O under real conditions of NOx streams. Zeolite samples of BEA, MFI and FER structures, of similar composition for each topology, but with basically different distribution of Al atoms in the framework, were either selected from commercial samples or prepared by the developed synthesis. The concentration of Al pairs and isolated Al atoms in the framework was determined by the combination of Si-29 MAS NMR and quantitative analysis of the Vis spectra of dehydrated Co-zeolites with Co(II) ions exchanged to a maximum degree. The structure, properties and activity of the counter Co, Cu and Fe ion species depending on the distribution of aluminium atoms in the framework between Al pairs of Al-O-(Si-O)(2)-Al sequences in one ring and isolated Al atoms (Al-O-(Si-O)(n>2)-Al sequences) in two rings are analyzed. The effect of the Al distribution on the activity of metal ion species is investigated for reactions of technology importance, i.e. SCR-NOx by propane, and decomposition of NO and N2O under real conditions of NOx streams. Zeolite samples of BEA, MFI and FER structures, of similar composition for each topology, but with basically different distribution of Al atoms in the framework, were either selected from commercial samples or prepared by the developed synthesis. The concentration of Al pairs and isolated Al atoms in the framework was determined by the combination of Si-29 MAS NMR and quantitative analysis of the Vis spectra of dehydrated Co-zeolites with Co(II) ions exchanged to a maximum degree. (en)
Title	Control of metal ion species in zeolites by distribution of aluminium in the framework: From structural analysis to performance under real conditions of SCR-NOx and NO, N2O decomposition Control of metal ion species in zeolites by distribution of aluminium in the framework: From structural analysis to performance under real conditions of SCR-NOx and NO, N2O decomposition (en)
skos:prefLabel	Control of metal ion species in zeolites by distribution of aluminium in the framework: From structural analysis to performance under real conditions of SCR-NOx and NO, N2O decomposition Control of metal ion species in zeolites by distribution of aluminium in the framework: From structural analysis to performance under real conditions of SCR-NOx and NO, N2O decomposition (en)
skos:notation	RIV/61388955:_____/11:00358402!RIV12-AV0-61388955
http://linked.open...avai/predkladatel	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(IAA400400904), P(KAN100400702), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika	1-2
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Wichterlová, Blanka Sobalík, Zdeněk Čapek, Libor Sazama, Petr Dědeček, Jiří
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	191915
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/11:00358402
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	zeolites; Co-BEA; Cu-MFI (en)
http://linked.open.../riv/klicoveSlovo	Co-BEA Cu-MFI zeolites
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[E9C6768C2CD3]
http://linked.open...i/riv/nazevZdroje	Applied Catalysis A - General
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	5 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	NMR crystallography of extraframework sites in silicon rich zeolites Nanostructured materials for catalytic, electrocatalytic and sorption applications
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	391
http://linked.open...iv/tvurceVysledku	Dědeček, Jiří Sazama, Petr Sobalík, Zdeněk Wichterlová, Blanka Čapek, Libor
http://linked.open...ain/vavai/riv/wos	000286856600030
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace
issn	0926-860X
number of pages	10 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.apcata.2010.06.026
is http://linked.open...avai/riv/vysledek of	Control of metal ion species in zeolites by distribution of aluminium in the framework: From structural analysis to performance under real conditions of SCR-NOx and NO, N2O decomposition Control of metal ion species in zeolites by distribution of aluminium in the framework: From structural analysis to performance under real conditions of SCR-NOx and NO, N2O decomposition

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