About: Co2+ Ions as Probes of Al Distribution in the Framework of Zeolites. ZSM-5 Study.     Goto   Sponge   Distinct   Permalink

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  • The occurrence of ôAl pairsö in the framework of ZSM-5 and their spatial distribution in zeolites was estimated by using exchanged Co2+ ions as probes for ôAl pairsö. The Vis spectra of Co2+ ions were employed to monitor the distribution of Co2+ ions, and thus ôAl pairsö, among the individual cationic sites, i.e. local framework arrangements at defined positions in the zeolite channels. The effects of concentration of aluminum in the framework and conditions of zeolite synthesis on the presence of ôAl pairsö and their spatial distribution in the ZSM-5 framework were investigated. It has been shown that the distribution of Al atoms in the framework is not controlled by statistic rules, but depends on the conditions of zeolite synthesis and aluminum concentration in the framework.
  • The occurrence of ôAl pairsö in the framework of ZSM-5 and their spatial distribution in zeolites was estimated by using exchanged Co2+ ions as probes for ôAl pairsö. The Vis spectra of Co2+ ions were employed to monitor the distribution of Co2+ ions, and thus ôAl pairsö, among the individual cationic sites, i.e. local framework arrangements at defined positions in the zeolite channels. The effects of concentration of aluminum in the framework and conditions of zeolite synthesis on the presence of ôAl pairsö and their spatial distribution in the ZSM-5 framework were investigated. It has been shown that the distribution of Al atoms in the framework is not controlled by statistic rules, but depends on the conditions of zeolite synthesis and aluminum concentration in the framework. (en)
Title
  • Co2+ Ions as Probes of Al Distribution in the Framework of Zeolites. ZSM-5 Study.
  • Co2+ Ions as Probes of Al Distribution in the Framework of Zeolites. ZSM-5 Study. (en)
skos:prefLabel
  • Co2+ Ions as Probes of Al Distribution in the Framework of Zeolites. ZSM-5 Study.
  • Co2+ Ions as Probes of Al Distribution in the Framework of Zeolites. ZSM-5 Study. (en)
skos:notation
  • RIV/61388955:_____/02:54020095!RIV/2003/AV0/A54003/N
http://linked.open.../vavai/riv/strany
  • 5406;5413
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  • P(OC D15.20), Z(AV0Z4040901)
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  • 641862
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  • RIV/61388955:_____/02:54020095
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  • Al distribution in zeolites; - ZSM-5; - Vis spectroscopy (en)
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  • GB - Spojené království Velké Británie a Severního Irska
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  • [F021C3F372F8]
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  • Physical Chemistry Chemical Physics
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  • 4
http://linked.open...iv/tvurceVysledku
  • Dědeček, Jiří
  • Wichterlová, Blanka
  • Kaucký, Dalibor
  • Gonsiorová, O.
http://linked.open...n/vavai/riv/zamer
issn
  • 1463-9076
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