About: Removal of CO Ligands from Pt Anionic Carbonyls in Zeolites by Heat Treatment in Vacuum or in Hydrogen Atmosphere and Following Subsequent Recarbonylation.     Goto   Sponge   Distinct   Permalink

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  • Pt anionic carbonyls were prepared by carbonylation of tetraamine ions in X, Y dealuminated Y, and EMT zeolites, by carbonylation of impregnated salts in MCM-41, NaBEA and NaM. These carbonyls were decomposed in vacuum and/or in hydrogen atmosphere and recarbonylated. It appeared that the recarbonylation after decomposition in vacuum proceeds readily in samples which exhibit higher basicity; with decreasing basicity carbonyls of higher nuclearity or lower negative charge are formed.
  • Pt anionic carbonyls were prepared by carbonylation of tetraamine ions in X, Y dealuminated Y, and EMT zeolites, by carbonylation of impregnated salts in MCM-41, NaBEA and NaM. These carbonyls were decomposed in vacuum and/or in hydrogen atmosphere and recarbonylated. It appeared that the recarbonylation after decomposition in vacuum proceeds readily in samples which exhibit higher basicity; with decreasing basicity carbonyls of higher nuclearity or lower negative charge are formed. (en)
Title
  • Removal of CO Ligands from Pt Anionic Carbonyls in Zeolites by Heat Treatment in Vacuum or in Hydrogen Atmosphere and Following Subsequent Recarbonylation.
  • Removal of CO Ligands from Pt Anionic Carbonyls in Zeolites by Heat Treatment in Vacuum or in Hydrogen Atmosphere and Following Subsequent Recarbonylation. (en)
skos:prefLabel
  • Removal of CO Ligands from Pt Anionic Carbonyls in Zeolites by Heat Treatment in Vacuum or in Hydrogen Atmosphere and Following Subsequent Recarbonylation.
  • Removal of CO Ligands from Pt Anionic Carbonyls in Zeolites by Heat Treatment in Vacuum or in Hydrogen Atmosphere and Following Subsequent Recarbonylation. (en)
skos:notation
  • RIV/61388955:_____/01:54010085!RIV/2003/AV0/A54003/N
http://linked.open.../vavai/riv/strany
  • 2704;2711
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  • P(IAA4040710), Z(AV0Z4040901)
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  • 13
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  • 694498
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  • RIV/61388955:_____/01:54010085
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  • Pt anionic carbonyl; - zeolites; - vacuum or hydrogen treatment (en)
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  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [5F4BDB8973BF]
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  • Physical Chemistry Chemical Physics
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  • 3
http://linked.open...iv/tvurceVysledku
  • Nováková, Jana
http://linked.open...n/vavai/riv/zamer
issn
  • 1463-9076
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