About: Experimental evidences for some unusual divalent cation complexes of valinomycin

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Z extrakčních dat v systému vodný roztok sole kationtu - nitrobenzen ? strontnatá sůl dikarbollylkobaltitanu byla spočtena rovnovážná extrakční konstanta reakce M2+ (aq) + 1.Sr2+ (nb) 1.M2+ (nb) + Sr2+ (aq) (M2+ = Cu2+, Zn2+, Cd2+, Pb2+, UO22+, Fe2+, Co2+, a Ni2+; 1 = valinomycin; aq =vodná fáze, nb = nitrobenzenová fáze). Konstanta stability komplexu 1.M2+ v nitrobenzenu, nasyceném vodou roste v pořadí Fe2+ < Cd2+, Co2+ < Ni2+ < UO22+, Zn2+ < Cu2+ < Pb2+. (cs) From extraction experiments and gamma-activity measurements, the exchange extraction constants corresponding to the general equilibrium M2+ (aq) + 1.Sr2+ (nb) 1.M2+ (nb) + Sr2+ (aq) taking place in the two-phase water-nitrobenzene system (M2+ = Cu2+, Zn2+, Cd2+, Pb2+, UO22+, Fe2+, Co2+, and Ni2+; 1 = valinomycin; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Moreover, the stability constants of the 1.M2+ complexes in water saturated nitrobenzene were calculated; they were found to increase in the order Fe2+ < Cd2+, Co2+ < Ni2+ < UO22+, Zn2+ < Cu2+ < Pb2+. From extraction experiments and gamma-activity measurements, the exchange extraction constants corresponding to the general equilibrium M2+ (aq) + 1.Sr2+ (nb) 1.M2+ (nb) + Sr2+ (aq) taking place in the two-phase water-nitrobenzene system (M2+ = Cu2+, Zn2+, Cd2+, Pb2+, UO22+, Fe2+, Co2+, and Ni2+; 1 = valinomycin; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Moreover, the stability constants of the 1.M2+ complexes in water saturated nitrobenzene were calculated; they were found to increase in the order Fe2+ < Cd2+, Co2+ < Ni2+ < UO22+, Zn2+ < Cu2+ < Pb2+. (en)
Title	Experimental evidences for some unusual divalent cation complexes of valinomycin Experimental evidences for some unusual divalent cation complexes of valinomycin (en) Experimentální důkaz tvorby komplexů některých dvojmocných kationtů s valinomycinem (cs)
skos:prefLabel	Experimental evidences for some unusual divalent cation complexes of valinomycin Experimental evidences for some unusual divalent cation complexes of valinomycin (en) Experimentální důkaz tvorby komplexů některých dvojmocných kationtů s valinomycinem (cs)
skos:notation	RIV/60461373:22340/08:00020705!RIV09-MSM-22340___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA104/05/2667), Z(MSM4977751303), Z(MSM6046137307)
http://linked.open...iv/cisloPeriodika	6
http://linked.open...vai/riv/dodaniDat	2009
http://linked.open...aciTvurceVysledku	Vaňura, Petr
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta chemicko-inženýrská
http://linked.open...dnocenehoVysledku	367189
http://linked.open...ai/riv/idVysledku	RIV/60461373:22340/08:00020705
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	antibiotics; macrocycles; complexation; stability constants; valinomycin (en)
http://linked.open.../riv/klicoveSlovo	valinomycin antibiotics macrocycles complexation stability constants
http://linked.open...odStatuVydavatele	DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV	[5F0B927D49F2]
http://linked.open...i/riv/nazevZdroje	Monatshefte für Chemie
http://linked.open...in/vavai/riv/obor	CB
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	Extraction methods for the isolation of fission products from radioactive waste by using new ecological solvents and fulfilling the needs of 21. centaury techno
http://linked.open...UplatneniVysledku	2008
http://linked.open...v/svazekPeriodika	139
http://linked.open...iv/tvurceVysledku	Makrlík, E. Vaňura, Petr Selucký, P.
http://linked.open...ain/vavai/riv/wos	000256324700003
http://linked.open...n/vavai/riv/zamer	Predikce poruch heterogenních materiálů, komponent mechanických a biomechanických systémů. Physico-chemical methods of analysis and characterization of chemical systems and biosystems
issn	0026-9247
number of pages	4 (xsd:int)
http://localhost/t...ganizacniJednotka	22340
is http://linked.open...avai/riv/vysledek of	Experimental evidences for some unusual divalent cation complexes of valinomycin Experimental evidences for some unusual divalent cation complexes of valinomycin Experimental evidences for some unusual divalent cation complexes of valinomycin Experimental evidences for some unusual divalent cation complexes of valinomycin

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