About: O, N-Chelated germanium, tin and lead compounds containing 2-[N,N-(dimethylamino)methyl] phenolate as ligand

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://www.sciencedirect.com/science/article/pii/S0022328X13001848
Description	Thirteen organotin(IV) and low valent complexes of group 14 (Ge, Sn, Pb) containing L-NO ligand(s) (where L-NO is 2-(N, N-dimethylaminomethyl) phenolate) were synthesized and its structure described by NMR techniques in solution and X-ray techniques in the solid state (for L2(NO)SnPh(2), (L2SnCl2)-Sn-NO, (L2Ge)-Ge-NO and (LSnCl)-Sn-NO which forms a dimer). Structures and properties of prepared species have been compared with previously published germanium and tin compounds containing -OCH2CH2NMe2 as O,N- or L-CN (where L-CN is 2-(N, N-dimethylaminomethyl) phenyl) as C, N-chelating ligands. The solid state structures containing L-NO ligand(s) reveal much stronger intramolecular N -} Sn coordination than complexes containing latter two ligands. Thirteen organotin(IV) and low valent complexes of group 14 (Ge, Sn, Pb) containing L-NO ligand(s) (where L-NO is 2-(N, N-dimethylaminomethyl) phenolate) were synthesized and its structure described by NMR techniques in solution and X-ray techniques in the solid state (for L2(NO)SnPh(2), (L2SnCl2)-Sn-NO, (L2Ge)-Ge-NO and (LSnCl)-Sn-NO which forms a dimer). Structures and properties of prepared species have been compared with previously published germanium and tin compounds containing -OCH2CH2NMe2 as O,N- or L-CN (where L-CN is 2-(N, N-dimethylaminomethyl) phenyl) as C, N-chelating ligands. The solid state structures containing L-NO ligand(s) reveal much stronger intramolecular N -} Sn coordination than complexes containing latter two ligands. (en)
Title	O, N-Chelated germanium, tin and lead compounds containing 2-[N,N-(dimethylamino)methyl] phenolate as ligand O, N-Chelated germanium, tin and lead compounds containing 2-[N,N-(dimethylamino)methyl] phenolate as ligand (en)
skos:prefLabel	O, N-Chelated germanium, tin and lead compounds containing 2-[N,N-(dimethylamino)methyl] phenolate as ligand O, N-Chelated germanium, tin and lead compounds containing 2-[N,N-(dimethylamino)methyl] phenolate as ligand (en)
skos:notation	RIV/00216275:25310/13:39896431!RIV14-GA0-25310___
http://linked.open...avai/predkladatel	Fakulta chemicko-technologická
http://linked.open...avai/riv/aktivita	I P S
http://linked.open...avai/riv/aktivity	I, P(GAP207/10/0215), S
http://linked.open...iv/cisloPeriodika	2013
http://linked.open...vai/riv/dodaniDat	2014
http://linked.open...aciTvurceVysledku	Novotný, Martin Růžička, Aleš Padělková, Zdeňka Holeček, Jaroslav
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	92755
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/13:39896431
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	XRD; NMR; phenolate; lead; tin; germanium (en)
http://linked.open.../riv/klicoveSlovo	germanium lead NMR XRD tin phenolate
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[213AA72E1EED]
http://linked.open...i/riv/nazevZdroje	Journal of Organometallic Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Structure, Properties and the Use of C,N-, Y,C,Y-chelated Organometallic and Related Metal Complexes
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	733
http://linked.open...iv/tvurceVysledku	Novotný, Martin Padělková, Zdeňka Růžička, Aleš Holeček, Jaroslav
http://linked.open...ain/vavai/riv/wos	000319194000012
issn	0022-328X
number of pages	8 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.jorganchem.2013.02.033
http://localhost/t...ganizacniJednotka	25310

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