About: Preparation and Structural Characterization of Simple and Donor-substituted Triorganostannyl 1'-(diphenylphosphino)-1-ferrocenecarboxylates and Their P-chalcogenide Derivatives

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Description	Triorganotin chlorides Me3SnCl and (L-NC)Me2SnCl (LNC = 2-[(dimethylamino)methyl]phenyl) reacted with potassium 1'-(diphenylphosphino)-1-ferrocenecarboxylate to give the respective carboxylates, Ph(2)PfcCO(2)SnMe(3) (1) and Ph(2)PfcCO(2)SnMe(2)(LNC) (2; fc = ferrocene-1,1'-diyl), while the analogous triphenylstannyl derivative 3 resulted by condensation of Ph3SnOH with 1'-(diphenylphosphino)-1-ferrocenecarboxylic acid (Hdpf). Compounds 1 and 2 were smoothly oxidized with hydrogen peroxide or elemental sulfur to afford the corresponding P-chalcogen derivatives (P-oxides 1a and 2a; P-sulfides 1b and 2b). All compounds were characterized by multinuclear NMR, IR and mass spectroscopy, and the solid-state structures of 1, 1a, 2, 2a and 2b were determined by single-crystal X-ray diffraction... Triorganotin chlorides Me3SnCl and (L-NC)Me2SnCl (LNC = 2-[(dimethylamino)methyl]phenyl) reacted with potassium 1'-(diphenylphosphino)-1-ferrocenecarboxylate to give the respective carboxylates, Ph(2)PfcCO(2)SnMe(3) (1) and Ph(2)PfcCO(2)SnMe(2)(LNC) (2; fc = ferrocene-1,1'-diyl), while the analogous triphenylstannyl derivative 3 resulted by condensation of Ph3SnOH with 1'-(diphenylphosphino)-1-ferrocenecarboxylic acid (Hdpf). Compounds 1 and 2 were smoothly oxidized with hydrogen peroxide or elemental sulfur to afford the corresponding P-chalcogen derivatives (P-oxides 1a and 2a; P-sulfides 1b and 2b). All compounds were characterized by multinuclear NMR, IR and mass spectroscopy, and the solid-state structures of 1, 1a, 2, 2a and 2b were determined by single-crystal X-ray diffraction... (en)
Title	Preparation and Structural Characterization of Simple and Donor-substituted Triorganostannyl 1'-(diphenylphosphino)-1-ferrocenecarboxylates and Their P-chalcogenide Derivatives Preparation and Structural Characterization of Simple and Donor-substituted Triorganostannyl 1'-(diphenylphosphino)-1-ferrocenecarboxylates and Their P-chalcogenide Derivatives (en)
skos:prefLabel	Preparation and Structural Characterization of Simple and Donor-substituted Triorganostannyl 1'-(diphenylphosphino)-1-ferrocenecarboxylates and Their P-chalcogenide Derivatives Preparation and Structural Characterization of Simple and Donor-substituted Triorganostannyl 1'-(diphenylphosphino)-1-ferrocenecarboxylates and Their P-chalcogenide Derivatives (en)
skos:notation	RIV/00216275:25310/10:39882010!RIV11-GA0-25310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/07/0468), Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika	2
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Růžička, Aleš
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	281351
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/10:39882010
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Cyclic voltammetry; Structure elucidation; Phosphine chalcogenides; Organotin esters; Phosphinocarboxylic ligands; Ferrocene (en)
http://linked.open.../riv/klicoveSlovo	Ferrocene Structure elucidation Cyclic voltammetry Organotin esters Phosphine chalcogenides Phosphinocarboxylic ligands
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[49215A629909]
http://linked.open...i/riv/nazevZdroje	Journal of Organometallic Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	Study of properties and the use of C,N- and Y,C,Y-chelated organometallic compounds
http://linked.open...UplatneniVysledku	2010
http://linked.open...v/svazekPeriodika	695
http://linked.open...iv/tvurceVysledku	Císařová, Ivana Růžička, Aleš Štěpnička, Petr
http://linked.open...ain/vavai/riv/wos	000273231700020
http://linked.open...n/vavai/riv/zamer	Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí
issn	0022-328X
number of pages	9 (xsd:int)
http://localhost/t...ganizacniJednotka	25310
is http://linked.open...avai/riv/vysledek of	Preparation and Structural Characterization of Simple and Donor-substituted Triorganostannyl 1'-(diphenylphosphino)-1-ferrocenecarboxylates and Their P-chalcogenide Derivatives Preparation and Structural Characterization of Simple and Donor-substituted Triorganostannyl 1'-(diphenylphosphino)-1-ferrocenecarboxylates and Their P-chalcogenide Derivatives Preparation and Structural Characterization of Simple and Donor-substituted Triorganostannyl 1'-(diphenylphosphino)-1-ferrocenecarboxylates and Their P-chalcogenide Derivatives

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