About: Mass spectrometric studies of silver complexes with a pyridine dicarboxamide ligand: interconversion of Ag(I) and Ag(III) oxidation states in the gas phase     Goto   Sponge   Distinct   Permalink

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Description
  • Electrospray ionization [ESI] enables the detection of highly unstable silver(III) complexes prepared in situ from the dicarboxamide ligand L (where L=N,N'-bis(2,6-diisopropylphenyl)-2,6-pyridinedicarboxamide) and Ag(CH3COO). The collision-induced dissociation of [Ag-III(L-H)(CH3COO)](+) leads to the elimination of oxiranone. As well as the silver(III) complexes, various other silver(I) complexes generated in the positive as well as negative ionization mode were investigated.
  • Electrospray ionization [ESI] enables the detection of highly unstable silver(III) complexes prepared in situ from the dicarboxamide ligand L (where L=N,N'-bis(2,6-diisopropylphenyl)-2,6-pyridinedicarboxamide) and Ag(CH3COO). The collision-induced dissociation of [Ag-III(L-H)(CH3COO)](+) leads to the elimination of oxiranone. As well as the silver(III) complexes, various other silver(I) complexes generated in the positive as well as negative ionization mode were investigated. (en)
Title
  • Mass spectrometric studies of silver complexes with a pyridine dicarboxamide ligand: interconversion of Ag(I) and Ag(III) oxidation states in the gas phase
  • Mass spectrometric studies of silver complexes with a pyridine dicarboxamide ligand: interconversion of Ag(I) and Ag(III) oxidation states in the gas phase (en)
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  • Mass spectrometric studies of silver complexes with a pyridine dicarboxamide ligand: interconversion of Ag(I) and Ag(III) oxidation states in the gas phase
  • Mass spectrometric studies of silver complexes with a pyridine dicarboxamide ligand: interconversion of Ag(I) and Ag(III) oxidation states in the gas phase (en)
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  • RIV/00216208:11310/12:10132690!RIV13-GA0-11310___
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  • I, P(GAP207/11/0338), Z(MSM0021620857)
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  • 5
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  • 148579
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  • RIV/00216208:11310/12:10132690
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  • oxidation states; silver complexes; dicarboxamide ligand; mass spectrometry; electrospray ionization (en)
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  • GB - Spojené království Velké Británie a Severního Irska
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  • [253A4B86B294]
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  • European Journal of Mass Spectrometry
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  • 18
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  • Roithová, Jana
  • Kumar, Pramod
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  • 000312762600006
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issn
  • 1469-0667
number of pages
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  • 10.1255/ejms.1195
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  • 11310
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