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  • In the last decade, we have experienced massive progress in spectroscopic methods for mass-selected ions. The aim of this tutorial review is to present action spectroscopy as a powerful tool for the investigation of ionic reaction intermediates. Examples span from ultraviolet and infrared photodissociation spectroscopy of model reaction intermediates to applications of infrared multiphoton dissociation spectroscopy (IRMPD) to intermediates directly sampled from reaction mixtures. The first example of double resonance IR-UV spectroscopy of model intermediates in an organometallic reaction is also mentioned.
  • In the last decade, we have experienced massive progress in spectroscopic methods for mass-selected ions. The aim of this tutorial review is to present action spectroscopy as a powerful tool for the investigation of ionic reaction intermediates. Examples span from ultraviolet and infrared photodissociation spectroscopy of model reaction intermediates to applications of infrared multiphoton dissociation spectroscopy (IRMPD) to intermediates directly sampled from reaction mixtures. The first example of double resonance IR-UV spectroscopy of model intermediates in an organometallic reaction is also mentioned. (en)
Title
  • Characterization of reaction intermediates by ion spectroscopy
  • Characterization of reaction intermediates by ion spectroscopy (en)
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  • Characterization of reaction intermediates by ion spectroscopy
  • Characterization of reaction intermediates by ion spectroscopy (en)
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  • RIV/00216208:11310/12:10128772!RIV13-MSM-11310___
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  • I, Z(MSM0021620857)
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  • 2
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  • 126835
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  • RIV/00216208:11310/12:10128772
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  • methanol; spectrometry; complexes; metal-ions; vibrational spectroscopy; infrared-spectroscopy; gas-phase oxidation; baylis-hillman reaction; cross-coupling reactions; electrospray-ionization mass (en)
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  • GB - Spojené království Velké Británie a Severního Irska
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  • [4F7DA477F778]
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  • Chemical Society Reviews
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  • 41
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  • Roithová, Jana
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  • 000298854900002
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  • 0306-0012
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  • 10.1039/c1cs15133a
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  • 11310
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