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rdf:type
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Description
| - A new amphiphilic block terpolymer poly((sulfamate-carboxylate)isoprene)-block-polystyrene-block-poly(ethylene oxide) was synthesized via the post polymerization reaction of the anionically prepared precursor block terpolymer polyisoprene-block-polystyrene-block-poly(ethylene oxide) with chlorosulfonyl isocyanate. The formation and structure of self-assemblies of the polyelectrolyte block terpolymer in dilute aqueous solutions were studied by light scattering, AFM, cryo-TEM, fluorometry, and H-1 NMR spectroscopy. In acidic solutions, the terpolymers self-assemble into kinetically trapped multicompartment micelles, with the core consisting of discrete PS and PISC domains and PEO in the shell. If the solution pH is adjusted to the alkaline region, the multicompartment micelles undergo an irreversible transition to regular micelles, with a PS core and a mixed shell formed by PEO and PISC blocks.
- A new amphiphilic block terpolymer poly((sulfamate-carboxylate)isoprene)-block-polystyrene-block-poly(ethylene oxide) was synthesized via the post polymerization reaction of the anionically prepared precursor block terpolymer polyisoprene-block-polystyrene-block-poly(ethylene oxide) with chlorosulfonyl isocyanate. The formation and structure of self-assemblies of the polyelectrolyte block terpolymer in dilute aqueous solutions were studied by light scattering, AFM, cryo-TEM, fluorometry, and H-1 NMR spectroscopy. In acidic solutions, the terpolymers self-assemble into kinetically trapped multicompartment micelles, with the core consisting of discrete PS and PISC domains and PEO in the shell. If the solution pH is adjusted to the alkaline region, the multicompartment micelles undergo an irreversible transition to regular micelles, with a PS core and a mixed shell formed by PEO and PISC blocks. (en)
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Title
| - Multicompartment Nanoparticles Formed by a Heparin-Mimicking Block Terpolymer in Aqueous Solutions
- Multicompartment Nanoparticles Formed by a Heparin-Mimicking Block Terpolymer in Aqueous Solutions (en)
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skos:prefLabel
| - Multicompartment Nanoparticles Formed by a Heparin-Mimicking Block Terpolymer in Aqueous Solutions
- Multicompartment Nanoparticles Formed by a Heparin-Mimicking Block Terpolymer in Aqueous Solutions (en)
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skos:notation
| - RIV/00216208:11310/09:10000214!RIV10-GA0-11310___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(GA203/07/0659), P(IAA401110702), Z(MSM0021620857)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/00216208:11310/09:10000214
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - ATOMIC FORCE MICROSCOPY; ABC TRIBLOCK COPOLYMER; LIGHT-SCATTERING (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - US - Spojené státy americké
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Procházka, Karel
- Uchman, Mariusz Marcin
- Štěpánek, Miroslav
- Mountrichas, Grigoris
- Pispas, Stergios
- Voets, Ilja K
- Walther, Andreas
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http://linked.open...ain/vavai/riv/wos
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://localhost/t...ganizacniJednotka
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is http://linked.open...avai/riv/vysledek
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