. "Fejfarov\u00E1, Karla" . . . "51" . "[BEE470991263]" . "0277-5387" . . . "Khalaji, A. D." . "Tahmasebi, V." . "Synthesis, characterization and crystal structure determination of a new vanadium(IV) Schiff base complex (VOL2) and investigation of its catalytic activity in the epoxidation of cyclooctene"@en . . "Du\u0161ek, Michal" . "The vanadium(IV) Schiff base complex VOL2, L = 2-{(E)-[2-chloroethyl)imino]methyl}-6-methoxy phenol, has been synthesized by the reaction of a methanolic solution of VO(acac)2 with a methanolic solution of the Schiff base ligand, and it has been characterized using single-crystal X-ray crystallography, elemental analysis (CHN) and FT-IR spectroscopy. The crystal structure determination of this complex shows a deformed tetragonal pyramidal N2O3 coordination sphere of the vanadium center. The Schiff base ligand acts as a bidentate ligand with the two phenolato oxygen atoms and the two imine nitrogen atoms in trans positions. Non-classical inter- and intra-molecular hydrogen bonds of the type C-H...O have been found in the structure. The catalytic activity of the VOL2 Schiff base complex in the epoxidation of cyclooctene was investigated using different reaction parameters."@en . . . "2"^^ . . . "Synthesis, characterization and crystal structure determination of a new vanadium(IV) Schiff base complex (VOL2) and investigation of its catalytic activity in the epoxidation of cyclooctene"@en . "vanadium (IV); Schiff base; single crystal; structure determination; catalysis; epoxidation"@en . "Synthesis, characterization and crystal structure determination of a new vanadium(IV) Schiff base complex (VOL2) and investigation of its catalytic activity in the epoxidation of cyclooctene" . "Grivani, G." . "The vanadium(IV) Schiff base complex VOL2, L = 2-{(E)-[2-chloroethyl)imino]methyl}-6-methoxy phenol, has been synthesized by the reaction of a methanolic solution of VO(acac)2 with a methanolic solution of the Schiff base ligand, and it has been characterized using single-crystal X-ray crystallography, elemental analysis (CHN) and FT-IR spectroscopy. The crystal structure determination of this complex shows a deformed tetragonal pyramidal N2O3 coordination sphere of the vanadium center. The Schiff base ligand acts as a bidentate ligand with the two phenolato oxygen atoms and the two imine nitrogen atoms in trans positions. Non-classical inter- and intra-molecular hydrogen bonds of the type C-H...O have been found in the structure. The catalytic activity of the VOL2 Schiff base complex in the epoxidation of cyclooctene was investigated using different reaction parameters." . "RIV/68378271:_____/13:00391676" . "109500" . . . "Synthesis, characterization and crystal structure determination of a new vanadium(IV) Schiff base complex (VOL2) and investigation of its catalytic activity in the epoxidation of cyclooctene" . . . "5"^^ . "10.1016/j.poly.2012.12.008" . . "I, P(GAP204/11/0809)" . "NL - Nizozemsko" . . . . "1" . "RIV/68378271:_____/13:00391676!RIV14-GA0-68378271" . . . "5"^^ . "Polyhedron" . . "000318958700007" .