. . "Polyaniline (PANI) films of submicrometer thickness were deposited in situ during the polymerization of aniline on polystyrene support. Aqueous poly(N-vinylpyrrolidone) solution was subsequently evaporated on the top of PANI films. During peeling off, the PANI film was transferred to a poly(N-vinylpyrrolidone) film. Both sides of the PANI film, the top surface of the film deposited on polystyrene, and the bottom surface originally in contact with a polystyrene dish, became subsequently available for the analysis by Raman and X-ray photoelectron spectroscopies. The molecular structures of both surfaces in protonated state were different, the top side corresponded to protonated emeraldine, while the bottom side to partly deprotonated cross-linked structure containing phenazine-like constitutional units. This result supports the concept of hydrophobic phenazine-like oligomers that are adsorbed at immersed surfaces during the oxidation of aniline, and PANI chains that grow from them, thus creating a brush-like PANI morphology."@en . . . . "adsorption; film formation; conducting polymer"@en . "5"^^ . "[59C3CC2DC114]" . "Synthetic Metals" . . "24" . "Mor\u00E1vkov\u00E1, Zuzana" . "000315248400033" . "10.1016/j.synthmet.2012.11.012" . . "Zemek, Josef" . "In situ polymerized polyaniline films: the top and the bottom"@en . . "In situ polymerized polyaniline films: the top and the bottom" . "Tom\u0161\u00EDk, Elena" . . . . "Stejskal, Jaroslav" . "1"^^ . "I, P(GAP205/12/0911), P(GPP108/11/P763), Z(AV0Z10100521), Z(AV0Z40500505)" . "0379-6779" . "RIV/68378271:_____/12:00386618" . . . . "In situ polymerized polyaniline films: the top and the bottom"@en . . "CH - \u0160v\u00FDcarsk\u00E1 konfederace" . "Trchov\u00E1, Miroslava" . "5"^^ . . . "162" . . "Polyaniline (PANI) films of submicrometer thickness were deposited in situ during the polymerization of aniline on polystyrene support. Aqueous poly(N-vinylpyrrolidone) solution was subsequently evaporated on the top of PANI films. During peeling off, the PANI film was transferred to a poly(N-vinylpyrrolidone) film. Both sides of the PANI film, the top surface of the film deposited on polystyrene, and the bottom surface originally in contact with a polystyrene dish, became subsequently available for the analysis by Raman and X-ray photoelectron spectroscopies. The molecular structures of both surfaces in protonated state were different, the top side corresponded to protonated emeraldine, while the bottom side to partly deprotonated cross-linked structure containing phenazine-like constitutional units. This result supports the concept of hydrophobic phenazine-like oligomers that are adsorbed at immersed surfaces during the oxidation of aniline, and PANI chains that grow from them, thus creating a brush-like PANI morphology." . . "In situ polymerized polyaniline films: the top and the bottom" . . "141024" . . "RIV/68378271:_____/12:00386618!RIV13-AV0-68378271" .