. . . "carbosilane dendrimers; cyclopentadienyl ligands; fluorine-containing ligands"@en . "RIV/67985858:_____/12:00375563!RIV13-AV0-67985858" . "Carbosilane Metallodendrimers with Cyclopentadienyldichlorotitanium(IV) End Groups" . . . . "\u010Cerm\u00E1k, Jan" . . "Dendritic polyols of the second and third generation 2G-OH8 (1), 2G-OH16 (2), and 3G-OH16 (3) were prepared by hydroboration/oxidation of allyl-terminated carbosilane dendrimers and used as supports for the immobilization of cyclopentadienyltrichlorotitanium(IV) complexes via alcoholysis. The reaction of 1 - 3 with CpTiCl3 gave metallodendrimers 2G-(OTiCpCl2)8 (4a), 2G-(OTiCpCl2)16 (5a), and 3G-(OTiCpCl2)16 (6a), respectively, whereas the reaction of 1 and 3 with CpSiFTiCl3 (CpSiF = C5H4SiMe2CH2CH2C8F17) yielded peripherally fluorinated metallodendrimers 2G-(OTiCpSiFCl2)8 (4b) and 3G-(OTiCpSiFCl2)16 (6b). The suggested structures were supported by comparison with model 1-propoxycomplexes 10a,b. To identify side products of the alcoholysis reaction, hydrolytic behavior of the starting trichloro complexes was studied both in solid state and in solution." . . . "8"^^ . "2" . "Carbosilane Metallodendrimers with Cyclopentadienyldichlorotitanium(IV) End Groups" . . "000301522300022" . "Dendritic polyols of the second and third generation 2G-OH8 (1), 2G-OH16 (2), and 3G-OH16 (3) were prepared by hydroboration/oxidation of allyl-terminated carbosilane dendrimers and used as supports for the immobilization of cyclopentadienyltrichlorotitanium(IV) complexes via alcoholysis. The reaction of 1 - 3 with CpTiCl3 gave metallodendrimers 2G-(OTiCpCl2)8 (4a), 2G-(OTiCpCl2)16 (5a), and 3G-(OTiCpCl2)16 (6a), respectively, whereas the reaction of 1 and 3 with CpSiFTiCl3 (CpSiF = C5H4SiMe2CH2CH2C8F17) yielded peripherally fluorinated metallodendrimers 2G-(OTiCpSiFCl2)8 (4b) and 3G-(OTiCpSiFCl2)16 (6b). The suggested structures were supported by comparison with model 1-propoxycomplexes 10a,b. To identify side products of the alcoholysis reaction, hydrolytic behavior of the starting trichloro complexes was studied both in solid state and in solution."@en . "1574-1443" . . "Carbosilane Metallodendrimers with Cyclopentadienyldichlorotitanium(IV) End Groups"@en . . "P(LC06070), Z(AV0Z40720504)" . . "Krupkov\u00E1, Alena" . "Journal of Inorganic and Organometallic Polymers and Materials" . . "RIV/67985858:_____/12:00375563" . "2"^^ . "10.1007/s10904-011-9632-1" . . . "NL - Nizozemsko" . . "22" . . "Carbosilane Metallodendrimers with Cyclopentadienyldichlorotitanium(IV) End Groups"@en . "2"^^ . . "[B33E322EE7F1]" . "125984" .