. "Karban, Jind\u0159ich" . . . "[25A1F6213EFE]" . . "10" . . "P(IAA400720703), P(IAA400720706), Z(AV0Z40550506), Z(AV0Z40720504), Z(MSM0021620857), Z(MSM0021627501)" . . "fluorinated hexopyranoses; synthesis; experiments"@en . . "Bud\u011B\u0161\u00EDnsk\u00FD, Milo\u0161" . "Pad\u011Blkov\u00E1, Z." . . "US - Spojen\u00E9 st\u00E1ty americk\u00E9" . "0022-3263" . . "RIV/67985858:_____/10:00343244" . . . "6"^^ . "000277531200033" . "Synthesis of All Configurational Isomers of 1,6-Anhydro-2,3,4-trideoxy-2,3-epimino-4-fluoro-\u03B2-D-hexopyranoses"@en . . "Fluorinated hexopyranoses are important synthetic targets because of their utilization as probes in enzymology, medicine and structure - reactivity studies. We have prepared a full series of 1,6-anhydro-2,3,4-deoxy-4-fluoro-2,3-epimino-\u03B2-D-hexopyranoses. The key step was reaction of trans-2,3-azidosulfonates possessing a free C-4 hydroxyl with DAST and subsequent LiAlH4 reduction. Nucleophilic displacement of the hydroxyl activated by DAST proceeded without rearrangement and with moderate to good yields. A convenient synthesis of D-manno epimine from a readily available 3-benzylamino derivative was also developed."@en . . "C\u00EDsa\u0159ov\u00E1, I." . "RIV/67985858:_____/10:00343244!RIV11-AV0-67985858" . "291512" . "Journal of Organic Chemistry" . "Synthesis of All Configurational Isomers of 1,6-Anhydro-2,3,4-trideoxy-2,3-epimino-4-fluoro-\u03B2-D-hexopyranoses" . . "Synthesis of All Configurational Isomers of 1,6-Anhydro-2,3,4-trideoxy-2,3-epimino-4-fluoro-\u03B2-D-hexopyranoses"@en . "75" . . "Fluorinated hexopyranoses are important synthetic targets because of their utilization as probes in enzymology, medicine and structure - reactivity studies. We have prepared a full series of 1,6-anhydro-2,3,4-deoxy-4-fluoro-2,3-epimino-\u03B2-D-hexopyranoses. The key step was reaction of trans-2,3-azidosulfonates possessing a free C-4 hydroxyl with DAST and subsequent LiAlH4 reduction. Nucleophilic displacement of the hydroxyl activated by DAST proceeded without rearrangement and with moderate to good yields. A convenient synthesis of D-manno epimine from a readily available 3-benzylamino derivative was also developed." . "2"^^ . . . "4"^^ . "Synthesis of All Configurational Isomers of 1,6-Anhydro-2,3,4-trideoxy-2,3-epimino-4-fluoro-\u03B2-D-hexopyranoses" . . "S\u00FDkora, Jan" . . "Kroutil, J." . . . .