. "000258394400012" . . . . "Palladium(II) Aryl-amido Complexes of Diphosphinoazines in Unsymmetrical PNP' Pincer-type Configuration" . . "RIV/67985858:_____/08:00312452" . . "diphosphinoazines; pincer complexes; aryl-amido complexes"@en . "Square planar palladium(II) aryl-amido complexes of diphosphinoazines in monoanionic unsymmetrical PNP pincer-type coordination were prepared by reactions of phenyl-, o-tolyl-, or 2,6-dimethylphenyllithium with previously described chloro-amido complexes of diphosphinoazines having isopropyl, cyclohexyl and tert-butyl substituents on phosphorus atoms. The compounds were characterized by NMR showing free rotation around metal-aryl bond in the complexes; the presence of Cipso \u2013 Pd bond was detected by two-dimensional experiments. In addition to that, crystal and molecular structure of two complexes was determined by x-ray diffraction. In both structures the ligand trans to the amide nitrogen is well surrounded by substituents on phosphorus atoms, the phenyl complex showing significant interactions between two cyclohexyl hydrogen atoms and the pi-system of the phenyl ring."@en . "Aryl-amidov\u00E9 komplexy palladia(II) s difosfinoaziny v nesymetrick\u00E9 kle\u0161\u0165ov\u00E9 PNP' konfiguraci"@cs . "S\u00FDkora, Jan" . . . . . "Palladium(II) Aryl-amido Complexes of Diphosphinoazines in Unsymmetrical PNP' Pincer-type Configuration"@en . . "5"^^ . . . . "Palladium(II) Aryl-amido Complexes of Diphosphinoazines in Unsymmetrical PNP' Pincer-type Configuration" . . . "Po\u0161ta, Martin" . "Square planar palladium(II) aryl-amido complexes of diphosphinoazines in monoanionic unsymmetrical PNP pincer-type coordination were prepared by reactions of phenyl-, o-tolyl-, or 2,6-dimethylphenyllithium with previously described chloro-amido complexes of diphosphinoazines having isopropyl, cyclohexyl and tert-butyl substituents on phosphorus atoms. The compounds were characterized by NMR showing free rotation around metal-aryl bond in the complexes; the presence of Cipso \u2013 Pd bond was detected by two-dimensional experiments. In addition to that, crystal and molecular structure of two complexes was determined by x-ray diffraction. In both structures the ligand trans to the amide nitrogen is well surrounded by substituents on phosphorus atoms, the phenyl complex showing significant interactions between two cyclohexyl hydrogen atoms and the pi-system of the phenyl ring." . "385815" . . "Journal of Organometallic Chemistry" . "4"^^ . . "P(GA203/01/0554), P(GA203/06/0738), P(LC06070), Z(AV0Z40720504), Z(MSM0021620857)" . . "Byly p\u0159ipraveny \u010Dtvercov\u011B plan\u00E1rn\u00ED aryl-amidov\u00E9 komplexy palladia(II) s difosfinoaziny koordinovan\u00FDmi jako monoanionick\u00E9 nesymetrick\u00E9 kle\u0161\u0165ov\u00E9 PNP ligandy reakc\u00ED fenyl-, o-tolyl- nebo 2,6-dimethylfenyllithia s ji\u017E d\u0159\u00EDve syntetizovan\u00FDmi chloro-amidov\u00FDmi komplexy difosfinoazin\u016F maj\u00EDc\u00EDch isopropylov\u00E9, cyklohexylov\u00E9 a tert-butylov\u00E9 substituenty na atomech fosforu. Slou\u010Deniny byly charakterizov\u00E1ny NMR, kter\u00E1 uk\u00E1zala volnou rotaci kolem vazby aryl-kov; p\u0159\u00EDtomnost vazby Cipso \u2013 Pd byla detekov\u00E1na dvoudimenzion\u00E1ln\u00EDmi experimenty. D\u00E1le byly pomoc\u00ED rentgenov\u00E9 difrakce ur\u010Deny krystalov\u00E9 a molekulov\u00E9 struktury dvou komplex\u016F. V obou struktur\u00E1ch je ligand trans k amidov\u00E9mu dus\u00EDku dob\u0159e obklopen substituenty na atomech fosforu p\u0159i\u010Dem\u017E fenylov\u00FD complex vykazuje v\u00FDznamnou interakci mezi dv\u011Bma cyklohexylov\u00FDmi atomy vod\u00EDku a pi-systemem fenylov\u00E9ho kruhu."@cs . . "Aryl-amidov\u00E9 komplexy palladia(II) s difosfinoaziny v nesymetrick\u00E9 kle\u0161\u0165ov\u00E9 PNP' konfiguraci"@cs . "RIV/67985858:_____/08:00312452!RIV09-AV0-67985858" . "CH - \u0160v\u00FDcarsk\u00E1 konfederace" . . . "Palladium(II) Aryl-amido Complexes of Diphosphinoazines in Unsymmetrical PNP' Pincer-type Configuration"@en . "18" . "693" . "[C460302AD95E]" . . "\u010Cerm\u00E1k, Jan" . "C\u00EDsa\u0159ov\u00E1, I." . "6"^^ . "Storch, Jan" . "0022-328X" .