"RIV/67985858:_____/07:00096242" . "Fluorofiln\u00ED vlastnosti (perfluoroktyl)ethyldimethylsilylsubstituovan\u00FDch a tetramethyl(perfluoralkyl)substituovan\u00FDch cyklopentadien\u016F a jejich Ti(IV), Rh(III), and Rh(I) komplex\u016F"@cs . "692" . . "Fluorophilic Properties of (Perfluorooctyl)ethyldimethylsilyl Substituted and Tetramethyl(perfluoroalkyl) Substituted Cyclopentadienes and Their Ti(IV), Rh(III), and Rh(I) Complexes" . . . . "Fluorophilic Properties of (Perfluorooctyl)ethyldimethylsilyl Substituted and Tetramethyl(perfluoroalkyl) Substituted Cyclopentadienes and Their Ti(IV), Rh(III), and Rh(I) Complexes" . "Fluorophilic Properties of (Perfluorooctyl)ethyldimethylsilyl Substituted and Tetramethyl(perfluoroalkyl) Substituted Cyclopentadienes and Their Ti(IV), Rh(III), and Rh(I) Complexes"@en . . "0022-328X" . . . "Fluorofiln\u00ED vlastnosti (perfluoroktyl)ethyldimethylsilylsubstituovan\u00FDch a tetramethyl(perfluoralkyl)substituovan\u00FDch cyklopentadien\u016F a jejich Ti(IV), Rh(III), and Rh(I) komplex\u016F"@cs . "[73223D9E4EA6]" . . . . "1974;1982" . "Kv\u00ED\u010Dala, J." . . "\u010Cervenkov\u00E1 \u0160\u0165astn\u00E1, Lucie" . "Byly ur\u010Deny fluorov\u00E9 rozd\u011Blovac\u00ED koeficienty v syst\u00E9mu perfluorhexan/toluen pro 37 fluorovan\u00FDch silylcyklopentadien\u016F, jejich komplex\u016F s titanem(IV), perfluoralkylsubstituovan\u00FDch tetramethylcyklopentadien\u016F a jejich Rh(III) a Rh(I) komplex\u016F. Specifick\u00E1 fluorofilita and fluornost podle Kisse a R\u00E1baie byly vypo\u010Dteny pro ka\u017Edou slou\u010Deninu s pomoc\u00ED molekul\u00E1rn\u00EDho objemu vypo\u010Dten\u00E9ho programem Gaussian. V\u00FDsledky ukazuj\u00ED malou relativn\u00ED d\u016Fle\u017Eitost parametru obsahu fluoru pro fluorofilitu, jak uk\u00E1z\u00E1no na p\u0159\u00EDkladu komplex\u016F rhodia(I), kter\u00E9 jsou fluorofiln\u00ED dokonce p\u0159i obsahu fluoru jen 46.3%. Podle o\u010Dek\u00E1v\u00E1n\u00ED vzrostla fluorofilita s d\u00E9lkou fluorov\u00E9ho ponytailu a po\u010Dtu ponytail\u016F v s\u00E9rii podobn\u00FDch slou\u010Denin, zat\u00EDmco pol\u00E1rn\u00ED M-Cl vazby ji sni\u017Eovaly. Fluorofility tautomer\u016F tetramethyl(perfluoralkyl)cyklopentadienu se zna\u010Dn\u011B m\u011Bnily, p\u0159esto\u017Ee byly zji\u0161t\u011Bny jen mal\u00E9 rozd\u00EDly v molekul\u00E1rn\u00EDm objemu. V\u011Bt\u0161ina sl"@cs . . . "9"^^ . . "Fluorous partition coefficients in perfluoromethylcyclohexane/toluene system for 37 fluorinated silylcyclopentadienes, titanium(IV) complexes derived from them, perfluoroalkyl substituted tetramethylcyclopentadienes, and their Rh(III) and Rh(I) complexes were determined. Specific fluorophilicity and fluorousness according to Kiss and R\u00E1bai was calculated for each compound with the help of molecular volume computed in the Gaussian program. The results show a relative unimportance of fluorine content parameter for fluorophilicity as shown by a rhodium(I) complex being fluorophilic at fluorine content as low as 46.3 %. As expected, fluorophilicity increased with the ponytail length and ponytail number in series of similar compounds, strong decrease of fluorophilicity in compounds containing polar M-Cl bonds was also observed. Fluorophilicities of tetramethyl(perfluoroalkyl)cyclopentadiene t"@en . "422270" . "Auerov\u00E1, Kate\u0159ina" . "fluorophilicity; fluorous cyclopentadienes; partition coefficient"@en . . . "10" . . "Fluorous partition coefficients in perfluoromethylcyclohexane/toluene system for 37 fluorinated silylcyclopentadienes, titanium(IV) complexes derived from them, perfluoroalkyl substituted tetramethylcyclopentadienes, and their Rh(III) and Rh(I) complexes were determined. Specific fluorophilicity and fluorousness according to Kiss and R\u00E1bai was calculated for each compound with the help of molecular volume computed in the Gaussian program. The results show a relative unimportance of fluorine content parameter for fluorophilicity as shown by a rhodium(I) complex being fluorophilic at fluorine content as low as 46.3 %. As expected, fluorophilicity increased with the ponytail length and ponytail number in series of similar compounds, strong decrease of fluorophilicity in compounds containing polar M-Cl bonds was also observed. Fluorophilicities of tetramethyl(perfluoroalkyl)cyclopentadiene t" . "4"^^ . "CH - \u0160v\u00FDcarsk\u00E1 konfederace" . "Journal of Organometallic Chemistry" . "RIV/67985858:_____/07:00096242!RIV08-AV0-67985858" . "\u010Cerm\u00E1k, Jan" . . "3"^^ . "P(IAA4072203), P(LC06070), Z(AV0Z40720504)" . . "Fluorophilic Properties of (Perfluorooctyl)ethyldimethylsilyl Substituted and Tetramethyl(perfluoroalkyl) Substituted Cyclopentadienes and Their Ti(IV), Rh(III), and Rh(I) Complexes"@en . .