"Srovn\u00E1n\u00ED vlastnost\u00ED zes\u00EDt\u011Bn\u00FDch vinylov\u00FDch polymer\u016F a polymo\u010Doviny jako optimalizovateln\u00FDch nosi\u010D\u016F katalyticky aktivn\u00EDch kovov\u00FDch nanoklastr\u016F. \u010C\u00E1st I. Nanometrick\u00E1 struktura polymo\u010Dovinov\u00E9ho nosi\u010De EnCatTM 40"@cs . "1-2" . "Cross-Linked Poly-Vinyl Polymers versus Polyureas as Designed Supports for Catalytically Active M0 Nanoclusters. Part I. Nanometer Scale Structure of the Polyurea Support EnCatTM 40" . . "Maniero, A. L." . "The cross-linked polymer EnCatTM 40 (polyurea) is investigated on the micro-(ESEM) and nanometer scale (ISEC, ESR, 13C CP MAS NMR) both in the dry (ESEM, 13C CP MAS NMR) and in the swollen state (ISEC, ESR, 13C CP MAS NMR). After swelling with THF or DMF, nanoporous domains featured by ca. 1.2 nm pores are clearly detected with ISEC. ESR analysis based on the evaluation of the rotational mobility of a suitable spin probe dissolved in THF, DMF, MeOH and PhCH3 as swelling media, does qualitatively confirm the presence of nanoporosity also in MeOH- and PhCH3-swollen EnCatTM 40. Our manifold analysis reveals the lack of any detectable nanoporosity in water."@en . . . "NL - Nizozemsko" . "Sassi, A. S." . "Cross-Linked Poly-Vinyl Polymers versus Polyureas as Designed Supports for Catalytically Active M0 Nanoclusters. Part I. Nanometer Scale Structure of the Polyurea Support EnCatTM 40" . . . "Zes\u00EDt\u011Bn\u00FD polymer EnCatTM 40 (polymo\u010Dovina) byl zkoum\u00E1n v mikrometrick\u00E9m (SEM) i nanometrick\u00E9m m\u011B\u0159\u00EDtku ((ISEC, ESR, 13C CP MAS NMR) a to jak v such\u00E9m stavu (ESEM, 13C CP MAS NMR), tak i ve zbobtnal\u00E9m stavu (ISEC, ESR, 13C CP MAS NMR). Po zbobtn\u00E1n\u00ED v THF nebo DMF, byly v polymeru pomoc\u00ED ISEC zji\u0161t\u011Bny nanopor\u00E9zn\u00ED dom\u00E9ny s p\u00F3ry o velikosti cca 1,2 nm. ESR m\u011B\u0159en\u00ED rota\u010Dn\u00ED mobility vhodn\u00E9 sondy v prost\u0159ed\u00ED THF, DMF, MeOH and PhCH3 kvalitativn\u011B potvrdila existenci nanoporozity v EnCatTM 40 zbobtnal\u00E9m v MeOH a v PhCH3. Na\u0161e mnohon\u00E1sobn\u00E1 anal\u00FDza prok\u00E1zala absenci jak\u00E9koli porozity ve vodn\u00E9m prost\u0159ed\u00ED."@cs . "Journal of Molecular Catalysis A-Chemical" . "RIV/67985858:_____/07:00091364!RIV08-AV0-67985858" . . "233;239" . . "[E7BC2CD55F45]" . "Pears, D." . "Z(AV0Z40720504)" . . "1381-1169" . "Corain, B." . . . . "Bolfa, C." . "7"^^ . "1"^^ . "275" . . "415328" . . "esr spectroscopy; functional resins; nanopores"@en . "Je\u0159\u00E1bek, Karel" . "Srovn\u00E1n\u00ED vlastnost\u00ED zes\u00EDt\u011Bn\u00FDch vinylov\u00FDch polymer\u016F a polymo\u010Doviny jako optimalizovateln\u00FDch nosi\u010D\u016F katalyticky aktivn\u00EDch kovov\u00FDch nanoklastr\u016F. \u010C\u00E1st I. Nanometrick\u00E1 struktura polymo\u010Dovinov\u00E9ho nosi\u010De EnCatTM 40"@cs . "Zoleo, A." . "RIV/67985858:_____/07:00091364" . "The cross-linked polymer EnCatTM 40 (polyurea) is investigated on the micro-(ESEM) and nanometer scale (ISEC, ESR, 13C CP MAS NMR) both in the dry (ESEM, 13C CP MAS NMR) and in the swollen state (ISEC, ESR, 13C CP MAS NMR). After swelling with THF or DMF, nanoporous domains featured by ca. 1.2 nm pores are clearly detected with ISEC. ESR analysis based on the evaluation of the rotational mobility of a suitable spin probe dissolved in THF, DMF, MeOH and PhCH3 as swelling media, does qualitatively confirm the presence of nanoporosity also in MeOH- and PhCH3-swollen EnCatTM 40. Our manifold analysis reveals the lack of any detectable nanoporosity in water." . "7"^^ . . "Cross-Linked Poly-Vinyl Polymers versus Polyureas as Designed Supports for Catalytically Active M0 Nanoclusters. Part I. Nanometer Scale Structure of the Polyurea Support EnCatTM 40"@en . "Cross-Linked Poly-Vinyl Polymers versus Polyureas as Designed Supports for Catalytically Active M0 Nanoclusters. Part I. Nanometer Scale Structure of the Polyurea Support EnCatTM 40"@en . .