"Z(AV0Z40720504)" . "Hydroboration of bi(cyclopent-1-ene) and 3,3'-biindene with borane, thexylborane or (\u2013)-isopinocampheylborane afforded, regardless of reaction conditions, meso-isomers of the corresponding diols as the main products. No reaction was observed with 9-BBN. The structure of both major and minor isomer of 1,1'-biindane-2,2'-diol was assigned on the basis of 1H NMR spectra of the corresponding Mosher\u2019s diesters. The stereochemistry of the meso-isomer of 1,1'-biindane-2,2'-diol was confirmed by a single-crystal X-ray analysis of the corresponding dimesylate. To explain the observed stereoselectivity, a theoretical study of the complexes of monohydroborated intermediate with borane was made using DFT methods."@en . . . "asymmetric hydroboration; dienes; dft calculations"@en . . "[01518AE5E415]" . . . "0010-0765" . . "71" . "478505" . "Baszczy\u0148ski, O." . . "CZ - \u010Cesk\u00E1 republika" . "Str\u00E1nsk\u00E1, D." . "000243130800008" . . "Krupkov\u00E1, Alena" . "Hydroborace 1,1'-bi(cyklopent-1-en)u a 3,3'-biindenu: experiment\u00E1ln\u00ED a teoretick\u00E1 studie."@cs . "Hydroboration of 1,1'-Bi(cyclopent-1-ene) and 3,3'-Biindene: Experimental and Theoretical Study." . "Hydroboration of 1,1'-Bi(cyclopent-1-ene) and 3,3'-Biindene: Experimental and Theoretical Study."@en . . "Hydroboration of 1,1'-Bi(cyclopent-1-ene) and 3,3'-Biindene: Experimental and Theoretical Study." . "Hydroborace bi(cyklopent-1-en)u a 3,3'-biindenu boranem, thexylboranem nebo (\u2013)-isopinocampheylboranem poskytla bez ohledu na reak\u010Dn\u00ED podm\u00EDnky meso-izomery odpov\u00EDdaj\u00EDc\u00EDch diol\u016F jako hlavn\u00ED produkt. V p\u0159\u00EDpad\u011B 9-BBN nebyla pozorov\u00E1na \u017E\u00E1dn\u00E1 reakce. Struktura jak majoritn\u00EDho, tak minoritn\u00EDho izomeru 1,1'-biindan-2,2'-diolu byla ur\u010Dena na z\u00E1klad\u011B 1H NMR spekter odpov\u00EDdaj\u00EDc\u00EDch Mosherov\u00FDch diester\u016F. Stereochemie meso-izomeru 1,1'-biindan-2,2'-diolu byla potvrzena rentgenovou strukturn\u00ED anal\u00FDzou odpov\u00EDdaj\u00EDc\u00EDho dimesyl\u00E1tu. Pro objasn\u011Bn\u00ED pozorovan\u00E9 stereoselektivity byla provedena teoretick\u00E1 studie komplex\u016F monohydroborovan\u00FDch intermedi\u00E1t\u016F s boranem metodami DFT."@cs . . "RIV/67985858:_____/06:00315817!RIV09-AV0-67985858" . . . "Kv\u00ED\u010Dala, J." . "Collection of Czechoslovak Chemical Communications" . "RIV/67985858:_____/06:00315817" . . "Hydroboration of 1,1'-Bi(cyclopent-1-ene) and 3,3'-Biindene: Experimental and Theoretical Study."@en . . "Hydroboration of bi(cyclopent-1-ene) and 3,3'-biindene with borane, thexylborane or (\u2013)-isopinocampheylborane afforded, regardless of reaction conditions, meso-isomers of the corresponding diols as the main products. No reaction was observed with 9-BBN. The structure of both major and minor isomer of 1,1'-biindane-2,2'-diol was assigned on the basis of 1H NMR spectra of the corresponding Mosher\u2019s diesters. The stereochemistry of the meso-isomer of 1,1'-biindane-2,2'-diol was confirmed by a single-crystal X-ray analysis of the corresponding dimesylate. To explain the observed stereoselectivity, a theoretical study of the complexes of monohydroborated intermediate with borane was made using DFT methods." . "11-12" . "Hydroborace 1,1'-bi(cyklopent-1-en)u a 3,3'-biindenu: experiment\u00E1ln\u00ED a teoretick\u00E1 studie."@cs . . "1"^^ . "16"^^ . "4"^^ .