"12" . "Pokorn\u00E1, Dana" . "[525BBCFF0FDB]" . "5"^^ . "Gal\u00EDkov\u00E1, Anna" . "Pulsed IR laser ablation of poly(ethylene succinate) results in the formation of volatile products (mainly carbon oxides, hydrogen, C1-C4 hydrocarbons) and affords deposition of polymeric films whose structure and molecular weight distribution, examined by EDX-SEM, FTIR, UV and NMR spectroscopy and gel-permeation chromatography, is virtually identical to the initial poly(ethylene succinate). The conventional thermal degradation of the deposited polymeric films and poly(ethylene succinate) has identical features confirming that the formation of the deposited films is controlled by depolymerization/repolymerization steps. Mechanism of thermal degradation is accounted for by random cleavages of polymer backbone and by molecular ester group interchange and/or a sequence of the C-C bond homolysis and recombination of the produced radicals." . . . "Pulsed IR laser ablation of poly(ethylene succinate) results in the formation of volatile products (mainly carbon oxides, hydrogen, C1-C4 hydrocarbons) and affords deposition of polymeric films whose structure and molecular weight distribution, examined by EDX-SEM, FTIR, UV and NMR spectroscopy and gel-permeation chromatography, is virtually identical to the initial poly(ethylene succinate). The conventional thermal degradation of the deposited polymeric films and poly(ethylene succinate) has identical features confirming that the formation of the deposited films is controlled by depolymerization/repolymerization steps. Mechanism of thermal degradation is accounted for by random cleavages of polymer backbone and by molecular ester group interchange and/or a sequence of the C-C bond homolysis and recombination of the produced radicals."@en . "480433" . "IR Laser Ablative Decomposition and Depolymerization/Repolymerization of Poly(ethylene succinate)" . . "P(GA104/04/2028), Z(AV0Z40320502), Z(AV0Z40720504)" . "Ablativn\u00ED rozklad a depolymerace / repolymerace polyethylensukcin\u00E1tu iniciovan\u00E9 I\u010C laserem"@cs . . . "RIV/67985858:_____/06:00055091" . . . . . "Blechta, Vratislav" . "Ablativn\u00ED rozklad a depolymerace / repolymerace polyethylensukcin\u00E1tu iniciovan\u00E9 I\u010C laserem"@cs . . "0141-3910" . "poly(ethylene succinate); laser degradation; laser-produced films"@en . "\u0160ubrt, Jan" . "Polymer Degradation and Stability" . "7"^^ . "NL - Nizozemsko" . . . . . . "3383;3389" . . . "4"^^ . "IR Laser Ablative Decomposition and Depolymerization/Repolymerization of Poly(ethylene succinate)"@en . "V\u00FDsledkem pulsn\u00ED I\u010C laserov\u00E9 ablace polyethylensukcin\u00E1tu je tvorba t\u011Bkav\u00FDch produkt\u016F ( hlavn\u011B oxidy uhl\u00EDku, vod\u00EDk, C1-C4 uhlovod\u00EDky ) a z\u00E1rove\u0148 se deponuje polymern\u00ED film, jeho\u017E struktura a distribuce molekulov\u00FDch hmotnost\u00ED ( zkouman\u00E1 EDX-SEM, FTIR, UV, NMR spektroskopi\u00ED a gelovou permea\u010Dn\u00ED chromatografi\u00ED ) jsou identick\u00E9 jako v p\u0159\u00EDpad\u011B v\u00FDchoz\u00EDho polyethylensukcin\u00E1tu. Konven\u010Dn\u00ED tepeln\u00FD rozklad deponovan\u00FDch polymern\u00EDch film\u016F a polyethylensukcin\u00E1tu m\u00E1 identick\u00E9 rysy, kter\u00E9 potvrzuj\u00ED, \u017Ee tvorba deponovan\u00FDch film\u016F je \u0159\u00EDzena depolymera\u010Dn\u00EDmi / repolymera\u010Dn\u00EDmi kroky. Mechanismus tepeln\u00E9ho rozkladu je vysv\u011Btlen n\u00E1hodn\u00FDm \u0161t\u011Bpen\u00EDm polymern\u00EDho \u0159et\u011Bzce a v\u00FDm\u011Bnou esterov\u00FDch skupin a/nebo homol\u00FDzou vazby C-C s n\u00E1slednou rekombinac\u00ED vytvo\u0159en\u00FDch radik\u00E1l\u016F."@cs . "IR Laser Ablative Decomposition and Depolymerization/Repolymerization of Poly(ethylene succinate)"@en . . . "91" . . "IR Laser Ablative Decomposition and Depolymerization/Repolymerization of Poly(ethylene succinate)" . . "RIV/67985858:_____/06:00055091!RIV07-AV0-67985858" . "Pola, Josef" .