. "Na modelov\u00E9m syst\u00E9mu sest\u00E1vaj\u00EDc\u00EDm z pop\u00EDlku ze spalovny komun\u00E1ln\u00EDho odpadu,chloridu m\u011Bdnat\u00E9ho,chloridu sodn\u00E9ho a aktivn\u00EDho uhl\u00ED v atmosf\u00E9\u0159e N2+10%O2 a p\u0159i 340\u00B0C byl studov\u00E1n vliv SO2, H2O2 a H2SO4 na de novo syntetick\u00E9 reakce PCDD/Fs. Na z\u00E1klad\u011B experiment\u00E1ln\u00EDch v\u00FDsledk\u016F a termodynamick\u00FDch v\u00FDpo\u010Dt\u016F byly navr\u017Eeny a diskutov\u00E1ny reak\u010Dn\u00ED mechanismy oxidativn\u00ED destrukce, konverse chloridu m\u011B\u010Fnat\u00E9ho na s\u00EDran a katalyzovan\u00E1 Deaconova reakce."@cs . "[8FBB55546B8E]" . . "Is it Possible by Thermodynamic Equilibrium Calculations to Judge the Presumable Reaction Mechanism?"@en . "Sborn\u00EDk p\u0159\u00EDsp\u011Bvk\u016F" . "Umo\u017E\u0148uje termodynamick\u00FD v\u00FDpo\u010Det p\u0159isp\u011Bt k objasn\u011Bn\u00ED reak\u010Dn\u00EDho mechanismu?"@cs . "Bure\u0161, M." . "Pek\u00E1rek, Vladim\u00EDr" . "Umo\u017E\u0148uje termodynamick\u00FD v\u00FDpo\u010Det p\u0159isp\u011Bt k objasn\u011Bn\u00ED reak\u010Dn\u00EDho mechanismu?" . . "Pardubice" . "1"^^ . "hotel Po\u013Eana u Hri\u0148ov\u00E9" . "80-7194-859-4" . "2006-05-22+02:00"^^ . . . "RIV/67985858:_____/06:00054924!RIV07-AV0-67985858" . "4"^^ . . . "Umo\u017E\u0148uje termodynamick\u00FD v\u00FDpo\u010Det p\u0159isp\u011Bt k objasn\u011Bn\u00ED reak\u010Dn\u00EDho mechanismu?"@cs . . . "29;32" . . . "Umo\u017E\u0148uje termodynamick\u00FD v\u00FDpo\u010Det p\u0159isp\u011Bt k objasn\u011Bn\u00ED reak\u010Dn\u00EDho mechanismu?" . "de novo synthesis; sulfur dioxide; hydrogen peroxide"@en . "In a laboratory model system consisting of fly ash from MWI, copper and sodium chloride and activated carbon in N2 + SO2 atmosphere and at 340oC, the de novo synthetic reactions of formation of PCDD/Fs were studied under laboratory conditions in the presence of sulfur dioxide, hydrogen peroxide, and sulfuric acid. On the basis of experimental results and thermodynamic calculations, the following mechanisms are proposed and discussed: oxidative destruction, conversion of cupric chloride to sulfate, and catalyzed Deacon reaction."@en . "Z(AV0Z40720504)" . "Na modelov\u00E9m syst\u00E9mu sest\u00E1vaj\u00EDc\u00EDm z pop\u00EDlku ze spalovny komun\u00E1ln\u00EDho odpadu,chloridu m\u011Bdnat\u00E9ho,chloridu sodn\u00E9ho a aktivn\u00EDho uhl\u00ED v atmosf\u00E9\u0159e N2+10%O2 a p\u0159i 340\u00B0C byl studov\u00E1n vliv SO2, H2O2 a H2SO4 na de novo syntetick\u00E9 reakce PCDD/Fs. Na z\u00E1klad\u011B experiment\u00E1ln\u00EDch v\u00FDsledk\u016F a termodynamick\u00FDch v\u00FDpo\u010Dt\u016F byly navr\u017Eeny a diskutov\u00E1ny reak\u010Dn\u00ED mechanismy oxidativn\u00ED destrukce, konverse chloridu m\u011B\u010Fnat\u00E9ho na s\u00EDran a katalyzovan\u00E1 Deaconova reakce." . . . . . "Univerzita Pardubice" . "Is it Possible by Thermodynamic Equilibrium Calculations to Judge the Presumable Reaction Mechanism?"@en . "RIV/67985858:_____/06:00054924" . "504961" . "2"^^ . .