. "7"^^ . "2"^^ . "Frenking, G." . . "The nature of the Ga-Ga bond in the naked dianion PhGaGaPh2- and its Na+-coordinated counterpart is discussed using the recently proposed formalism based on the analysis of domain-averaged Fermi holes. The analysis shows clearly that three electron pairs, i.e., two sigma and one pi, contribute to the Ga-Ga bonding interactions in the free dianion PhGaGaPh2- and in the sodium-complexed species (PhGaGaPh)Na-2. The eigenvalues and the eigenvectors of the Fermi hole indicate, however, that the Ga-Ga bonding situation does not correspond to classical triple bonds and should not be interpreted using classical bonding models"@en . "Ga-Ga bonding;domain averaged fermi holes"@en . "8" . "23" . . "0276-7333" . "Chemick\u00E1 struktura z analysy dom\u00E9nov\u011B pr\u016Fm\u011Brovan\u00FDch Fermiho d\u011Br. Povaha vazby GaGa v PhGaGaPh(2-) a PhGaGaPhNa2"@cs . "Juzhakov, Gleb" . . "RIV/67985858:_____/04:00104855" . "Ponec, Robert" . "Chemical Structures from the Analysis of Domain Averaged Fermi holes. The Nature of GaGa Bonding in PhGaGaPh(2-) and PhGaGaPhNa2" . . . . "P(IAA4072006), Z(AV0Z4072921)" . . . . "Chemical Structures from the Analysis of Domain Averaged Fermi holes. The Nature of GaGa Bonding in PhGaGaPh(2-) and PhGaGaPhNa2"@en . . "Povaha vazby GaGa v dianiontu PhGaGaPh(2-) a jeho dvojn\u00E1sobn\u011B Na+ koordinovan\u00E9 soli je diskutov\u00E1na pomoc\u00ED ned\u00E1vno navr\u017Een\u00E9ho formalismu zalo\u017Een\u00E9ho na analyse dom\u00E9nov\u011B pr\u016Fm\u011Brovan\u00FDch Fermiho d\u011Br. Analysa uk\u00E1zala, \u017Ee k vazb\u011B v obou slou\u010Denin\u00E1ch p\u0159isp\u00EDvaj\u00ED 3 elektronov\u00E9 p\u00E1ry tvo\u0159\u00EDc\u00ED jednu pi a dv\u011B sigma komponenty. Vlastn\u00ED hodnoty a vlastn\u00ED vektory p\u0159\u00EDslu\u0161n\u00FDch Fermiho d\u011Br ukazuj\u00ED, \u017Ee vazba neodpov\u00EDd\u00E1 klasick\u00E9 trojn\u00E9 vazb\u011B a \u017Ee nem\u016F\u017Ee b\u00FDt interpretov\u00E1na pomoc\u00ED klasick\u00E9ho modelu chemick\u00E9 vazby"@cs . "Organometallics" . . . "The nature of the Ga-Ga bond in the naked dianion PhGaGaPh2- and its Na+-coordinated counterpart is discussed using the recently proposed formalism based on the analysis of domain-averaged Fermi holes. The analysis shows clearly that three electron pairs, i.e., two sigma and one pi, contribute to the Ga-Ga bonding interactions in the free dianion PhGaGaPh2- and in the sodium-complexed species (PhGaGaPh)Na-2. The eigenvalues and the eigenvectors of the Fermi hole indicate, however, that the Ga-Ga bonding situation does not correspond to classical triple bonds and should not be interpreted using classical bonding models" . . "Chemical Structures from the Analysis of Domain Averaged Fermi holes. The Nature of GaGa Bonding in PhGaGaPh(2-) and PhGaGaPhNa2"@en . "Giron\u00E9s, X." . "Chemick\u00E1 struktura z analysy dom\u00E9nov\u011B pr\u016Fm\u011Brovan\u00FDch Fermiho d\u011Br. Povaha vazby GaGa v PhGaGaPh(2-) a PhGaGaPhNa2"@cs . "[F2D452D2CFDA]" . "1790;1796" . "557531" . "US - Spojen\u00E9 st\u00E1ty americk\u00E9" . . "RIV/67985858:_____/04:00104855!RIV/2005/AV0/A27005/N" . "4"^^ . "Chemical Structures from the Analysis of Domain Averaged Fermi holes. The Nature of GaGa Bonding in PhGaGaPh(2-) and PhGaGaPhNa2" . . .