. . "4"^^ . . . "Kv\u00ED\u010Dala, J." . "Trimethylsilylcyklopentadieny s polyfluorovan\u00FDmi ohony and mono- a bis(h5-cyklopentadienyl)titani\u010Dit\u00E9 komplexy od nich odvozen\u00E9"@cs . "All the cyclopentadienes were found, in analogy with similar known compounds, to be mixtures of isomers between which prototropic and on the NMR time scale fast metallotropic shifts occurred, as confirmed by variable-temperature 1H and 13C NMR. The reaction of 4 with TiCl4 gave Ti(IV) complex [{5-C5H4Si(CH3)2CH2CH2C8F17}TiCl3] (5), whereas the reaction of [(C5H4SiMe3)TiCl3] with lithium salts of 1 and 2 yielded complexes [{5-C5H4Si(CH3)2CH2CH2C8F17}{5-C5H4Si(CH3)3}TiCl2] (6) and [{5-C5H3(Si(CH3)2CH2CH2C8F17)2}{5-C5H4Si(CH3)3}TiCl2] (7), respectively. The results show the applicability of fluorous chemistry methodology in early transition metal organometallic chemistry" . "5"^^ . "[AADCA562A58F]" . . "Trimethylsilylcyclopentadienes with Polyfluorinated Ponytails and Mono- and Bis(?5-cyclopentadienyl)titanium(IV) Complexes Derived from Them" . . "0276-7333" . . . "C\u00EDsa\u0159ov\u00E1, I." . "23" . . . "3"^^ . "RIV/67985858:_____/04:00104797" . "RIV/67985858:_____/04:00104797!RIV/2005/GA0/A27005/N" . . "590886" . . . . . . "Organometallics" . "Trimethylsilylcyklopentadieny s polyfluorovan\u00FDmi ohony and mono- a bis(h5-cyklopentadienyl)titani\u010Dit\u00E9 komplexy od nich odvozen\u00E9"@cs . . . "2850;2854" . . . "All the cyclopentadienes were found, in analogy with similar known compounds, to be mixtures of isomers between which prototropic and on the NMR time scale fast metallotropic shifts occurred, as confirmed by variable-temperature 1H and 13C NMR. The reaction of 4 with TiCl4 gave Ti(IV) complex [{5-C5H4Si(CH3)2CH2CH2C8F17}TiCl3] (5), whereas the reaction of [(C5H4SiMe3)TiCl3] with lithium salts of 1 and 2 yielded complexes [{5-C5H4Si(CH3)2CH2CH2C8F17}{5-C5H4Si(CH3)3}TiCl2] (6) and [{5-C5H3(Si(CH3)2CH2CH2C8F17)2}{5-C5H4Si(CH3)3}TiCl2] (7), respectively. The results show the applicability of fluorous chemistry methodology in early transition metal organometallic chemistry"@en . "P(GA203/99/M037), P(IAA4072005), P(IAA4072203), Z(AV0Z4072921)" . "12" . "\u010Cerm\u00E1k, Jan" . . "Trimethylsilylcyclopentadienes with Polyfluorinated Ponytails and Mono- and Bis(?5-cyclopentadienyl)titanium(IV) Complexes Derived from Them"@en . "\u0160\u0165astn\u00E1, Lucie" . "Trimethylsilylcyclopentadienes with Polyfluorinated Ponytails and Mono- and Bis(?5-cyclopentadienyl)titanium(IV) Complexes Derived from Them" . "Trimethylsilylcyclopentadienes with Polyfluorinated Ponytails and Mono- and Bis(?5-cyclopentadienyl)titanium(IV) Complexes Derived from Them"@en . "S\u00FDkora, Jan" . "V analogii s podobn\u00FDmi zn\u00E1m\u00FDmi slou\u010Deninami bylo zji\u0161t\u011Bno, \u017Ee v\u0161echny cyklopentadieny jsou sm\u011Bsi izomer\u016F, mezi kter\u00FDmi prob\u00EDhaj\u00ED prototropn\u00ED a na NMR \u010Dasov\u00E9 \u0161k\u00E1le rychl\u00E9 metalotropn\u00ED posuny, co\u017E bylo potvrzeno 1H and 13C NMR spektroskopi\u00ED za prom\u011Bnn\u00E9 teploty. Reaction 4 s TiCl4 d\u00E1v\u00E1 Ti(IV) komplex [{5-C5H4Si(CH3)2CH2CH2C8F17}TiCl3] (5), zat\u00EDmco reakce [(C5H4SiMe3)TiCl3] s lithn\u00FDmi solemi 1 a 2 poskytla komplexy [{5-C5H4Si(CH3)2CH2CH2C8F17}{5-C5H4Si(CH3)3}TiCl2] (6) and [{5-C5H3(Si(CH3)2CH2CH2C8F17)2}{5-C5H4Si(CH3)3}TiCl2] (7). V\u00FDsledky ukazuj\u00ED na aplikovatelnost metodologie fluorov\u00E9 chemie v chemii p\u0159echodn\u00FDch kov\u016F z po\u010D\u00E1tku periody"@cs . "US - Spojen\u00E9 st\u00E1ty americk\u00E9" . "molecular structure;organometallic chemistry;methodology"@en .