"http://isdv.upv.cz/portal/pls/portal/portlets.pts.det?xprim=1415911&lan=cs" . . . . . "Zp\u016Fsob v\u00FDroby titanosilik\u00E1tu Ti-ZSM-5 s MFI strukturou"@cs . "304248" . . "\u00DA\u0159ad pr\u016Fmyslov\u00E9ho vlastnictv\u00ED" . . . "Hol\u00EDkov\u00E1, Stanislava" . . "[C4D350DB08FF]" . "Zp\u016Fsob v\u00FDroby titanosilik\u00E1tu Ti-ZSM-5 s MFI strukturou" . "3"^^ . . "Process for preparing titanosilicate Ti-ZSM-5 with MFI structure"@en . . "3"^^ . . "In the present invention, there is disclosed a process for preparing titanium silicate Ti-ZSM-5 with MFI structure corresponding to aluminosilicate zeolite ZSM-5 from a liquid mixture of Si and Ti tetraalkoxides through a controlled hydrolysis with an aqueous solution of tetrapropylammonium hydroxide and with subsequent evaporation of ethanol and then through a hydrothermal synthesis within an autoclave with subsequent separation of colloidal crystals of titanium silicate Ti-ZSM-5, wherein the preparation process of the present invention is characterized in that in the course of the hydrothermal synthesis, the amount of water in the reaction mixture corresponds to the molar ratio of Hi2O/Si = 7 to 10/1, what makes it possible to obtain a sufficient concentration of the reaction mixture for a quick formation of the MFI structure, whereby the reaction components are present in the form of a solution or a colloidal sol."@en . "Prague" . "Zp\u016Fsob v\u00FDroby titanosilik\u00E1tu Ti-ZSM-5 s MFI strukturou odpov\u00EDdaj\u00EDc\u00ED aluminosilik\u00E1tov\u00E9mu zeolitu ZSM-5 z kapaln\u00E9 sm\u011Bsi tetraalkoxid\u016F Si a Ti \u0159\u00EDzenou hydrol\u00FDzou vodn\u00FDm roztokem tetrapropylamoniumhydroxidu s n\u00E1sledn\u00FDm odpa\u0159en\u00EDm ethanolu a pot\u00E9 hydroterm\u00E1ln\u00ED synt\u00E9zou v autokl\u00E1vu s n\u00E1slednou separac\u00ED koloidn\u00EDch krystal\u016F titanosilik\u00E1tu Ti-ZSM-5 spo\u010D\u00EDv\u00E1 v tom, \u017Ee obsah vody v reak\u010Dn\u00ED sm\u011Bsi p\u0159i hydroterm\u00E1ln\u00ED synt\u00E9ze odpov\u00EDd\u00E1 mol\u00E1rn\u00EDmu pom\u011Bru H₂O/Si = 7 a\u017E 10/1, co\u017E umo\u017E\u0148uje dostate\u010Dnou koncentraci reak\u010Dn\u00ED sm\u011Bsi pro rychl\u00FD vznik struktury MFI, p\u0159i\u010Dem\u017E reak\u010Dn\u00ED slo\u017Eky jsou p\u0159\u00EDtomny ve form\u011B roztoku \u010Di koloidn\u00EDho solu."@cs . "P(FT-TA3/080)" . "Zp\u016Fsob v\u00FDroby titanosilik\u00E1tu Ti-ZSM-5 s MFI strukturou"@cs . "Process for preparing titanosilicate Ti-ZSM-5 with MFI structure"@en . . . . "RIV/62243136:_____/13:MPOPV497" . . "RIV/62243136:_____/13:MPOPV497!RIV14-MPO-62243136" . . "Dole\u017Eal, Ji\u0159\u00ED" . "2013-12-18+01:00"^^ . . . "Zp\u016Fsob v\u00FDroby titanosilik\u00E1tu Ti-ZSM-5 s MFI strukturou odpov\u00EDdaj\u00EDc\u00ED aluminosilik\u00E1tov\u00E9mu zeolitu ZSM-5 z kapaln\u00E9 sm\u011Bsi tetraalkoxid\u016F Si a Ti \u0159\u00EDzenou hydrol\u00FDzou vodn\u00FDm roztokem tetrapropylamoniumhydroxidu s n\u00E1sledn\u00FDm odpa\u0159en\u00EDm ethanolu a pot\u00E9 hydroterm\u00E1ln\u00ED synt\u00E9zou v autokl\u00E1vu s n\u00E1slednou separac\u00ED koloidn\u00EDch krystal\u016F titanosilik\u00E1tu Ti-ZSM-5 spo\u010D\u00EDv\u00E1 v tom, \u017Ee obsah vody v reak\u010Dn\u00ED sm\u011Bsi p\u0159i hydroterm\u00E1ln\u00ED synt\u00E9ze odpov\u00EDd\u00E1 mol\u00E1rn\u00EDmu pom\u011Bru H₂O/Si = 7 a\u017E 10/1, co\u017E umo\u017E\u0148uje dostate\u010Dnou koncentraci reak\u010Dn\u00ED sm\u011Bsi pro rychl\u00FD vznik struktury MFI, p\u0159i\u010Dem\u017E reak\u010Dn\u00ED slo\u017Eky jsou p\u0159\u00EDtomny ve form\u011B roztoku \u010Di koloidn\u00EDho solu." . . "119363" . . . "V\u00FDzkumn\u00FD \u00FAstav anorganick\u00E9 chemie, a. s., \u00DAst\u00ED nad Labem" . . "titanosilicate, zeolite, MFI structure"@en . "Zp\u016Fsob v\u00FDroby titanosilik\u00E1tu Ti-ZSM-5 s MFI strukturou" . "Tokarov\u00E1, V\u011Bnceslava" . . .