"Reactions of double tucked-in permethyltitanocene [Ti{eta3:eta4-C5Me3(CH2)2}(eta5-C5Me5)] (1) with t-butanol or propargyl alcohol in toluene proceeded sluggishly even with excess of the alcohol and at elevated temperature. The alcoholysis of 1 with t-butanol afforded [Ti(eta5-C5Me5)(Ot-Bu)3] (3) as the major product and Ti(OtBu)4 as the minor one. The other product of the alcoholysis was pentamethylcyclopentadiene. The only isolated crystalline product was the very minor hydrolytic byproduct [{TiIII(eta5-C5Me5)2}(mu-O){TiIV(Ot-Bu)3}] (2). The alcoholysis of 1 containing traces of LiI with HOCH2C=CH, containing apparently more water than t-BuOH, gave an inseparable mixture of oily products from which several crystals of an unintended hydrolytic byproduct [{Ti(eta5-C5Me5)(OCH2C=CH)(mu-O)}3LiI] (4) were isolated. X-ray crystal structures of 2 and 4 were determined." . "391543" . "Reactions of doubly tucked-in permethyltitanocene with t-butanol and propargyl alcohol. The crystal structures of unusual hydrolytic byproducts."@en . "8 - 9" . "Reactions of double tucked-in permethyltitanocene [Ti{eta3:eta4-C5Me3(CH2)2}(eta5-C5Me5)] (1) with t-butanol or propargyl alcohol in toluene proceeded sluggishly even with excess of the alcohol and at elevated temperature. The alcoholysis of 1 with t-butanol afforded [Ti(eta5-C5Me5)(Ot-Bu)3] (3) as the major product and Ti(OtBu)4 as the minor one. The other product of the alcoholysis was pentamethylcyclopentadiene. The only isolated crystalline product was the very minor hydrolytic byproduct [{TiIII(eta5-C5Me5)2}(mu-O){TiIV(Ot-Bu)3}] (2). The alcoholysis of 1 containing traces of LiI with HOCH2C=CH, containing apparently more water than t-BuOH, gave an inseparable mixture of oily products from which several crystals of an unintended hydrolytic byproduct [{Ti(eta5-C5Me5)(OCH2C=CH)(mu-O)}3LiI] (4) were isolated. X-ray crystal structures of 2 and 4 were determined."@en . "P(FT-TA3/078), P(LC06070), V, Z(AV0Z40400503), Z(MSM0021620857)" . . . . "Reactions of doubly tucked-in permethyltitanocene with t-butanol and propargyl alcohol. The crystal structures of unusual hydrolytic byproducts." . "titanium, double tucked-in titanocene, alcoholysis, crystal structures"@en . "Pinkas, J." . . "0010-0765" . "[879BE3ADF06C]" . . "Mach, Karel" . "\u0160t\u011Bpni\u010Dka, P." . . . . . "C\u00EDsa\u0159ov\u00E1, I." . "CZ - \u010Cesk\u00E1 republika" . . . "2"^^ . . . "RIV/62243136:_____/08:#0000055" . . . "RIV/62243136:_____/08:#0000055!RIV11-MPO-62243136" . "Reactions of doubly tucked-in permethyltitanocene with t-butanol and propargyl alcohol. The crystal structures of unusual hydrolytic byproducts."@en . . . . "8"^^ . . . "16"^^ . "Gyepes, R." . "Reactions of doubly tucked-in permethyltitanocene with t-butanol and propargyl alcohol. The crystal structures of unusual hydrolytic byproducts." . "Hor\u00E1\u010Dek, M." . "Collection of Czechoslovak Chemical Communications" . . "73 (2008)" . . "Kubi\u0161ta, J." . "Varga, Vojt\u011Bch" .