. "New York" . "2014-05-26+02:00"^^ . . "http://scitation.aip.org/docserver/fulltext/aip/proceeding/aipcp/1622/10.1063/1.4898606/1.4898606.pdf?expires=1424094662&id=id&accname=guest&checksum=DE6DA0BDAD68D5EA13B3ACBFD7528F7A" . . "Fe-bearing garnets, thermal behavior, reducing atmosphere, iron particles, M\u00F6ssbauer spectroscopy."@en . "21671" . . . "The influence of the iron content on the reductive decomposition of A 3?x Fe x Al 2 Si 3 O 12 garnets (A = Mg, Mn; 0.47 ? x ? 2.85)"@en . . "Aparicio Ordonez, Claudia Jeannette Sarita" . "[FA8B3E88471D]" . . "10.1063/1.4898606" . "978-0-7354-1259-0" . . "RIV/61989592:15310/14:33152231!RIV15-MSM-15310___" . "The influence of the iron content on the reductive decomposition of A 3?x Fe x Al 2 Si 3 O 12 garnets (A = Mg, Mn; 0.47 ? x ? 2.85)" . "15310" . . "P(ED2.1.00/03.0058), P(EE2.3.20.0017), P(EE2.3.20.0056), P(EE2.3.20.0155), P(LH12079)" . . . . "Zbo\u0159il, Radek" . . . . "RIV/61989592:15310/14:33152231" . . "000345961800003" . "The influence of the iron content on the reductive decomposition of A 3?x Fe x Al 2 Si 3 O 12 garnets (A = Mg, Mn; 0.47 ? x ? 2.85)"@en . "0094-243X" . . . "Thermally-induced reductive decomposition of natural iron-bearing garnets of the almandine-pyrope and almandine-spessartine series were studied at temperatures up to 1200 \u00B0C (heating rate of 10 \u00B0C/min) under atmosphere of forming gas (10% of H2 in N2). Crystallochemical formula of the studied garnet was calculated as VIII(A3-xFe2+ x)VI(Al, Fe3+)2Si3O12, where the amount of Fe3+ in the octahedral sites is negligible with the exception of pyrope, A = Mg, Mn, and 0.47 ? x ? 2.85. The observed decomposition temperature, determined from differential scanning calorimetry and thermogravimetry, is greater than 1000 \u00B0C in all cases and showed almost linear dependence on the iron content in the dodecahedral sites of the studied garnets, with the exception of garnet with a near-pyrope composition (Prp80Alm20). The initial garnet samples and decomposition products were characterized in details by means of X-ray powder diffraction and 57Fe M\u00F6ssbauer spectroscopy. We found that all studied garnets have common decomposition products such as metallic iron (in general, rounded particles below 4 m\u00FDm) and Fe-spinel; the other identified decomposition products depend on starting chemical composition of the garnet: Fe-cordierite, olivine (fayalite or tephroite), cristobalite, pyroxene (enstatite or pigeonite), and anorthite. Anorthite and pigeonite were only present in garnets with Ca in the dodecahedral site. All the identified phases were usually well crystallized."@en . "4"^^ . . "The influence of the iron content on the reductive decomposition of A 3?x Fe x Al 2 Si 3 O 12 garnets (A = Mg, Mn; 0.47 ? x ? 2.85)" . . "4"^^ . "13"^^ . "AIP Conference Proceedings" . "Aparicio Ordonez, Claudia Jeannette Sarita" . . . "Thermally-induced reductive decomposition of natural iron-bearing garnets of the almandine-pyrope and almandine-spessartine series were studied at temperatures up to 1200 \u00B0C (heating rate of 10 \u00B0C/min) under atmosphere of forming gas (10% of H2 in N2). Crystallochemical formula of the studied garnet was calculated as VIII(A3-xFe2+ x)VI(Al, Fe3+)2Si3O12, where the amount of Fe3+ in the octahedral sites is negligible with the exception of pyrope, A = Mg, Mn, and 0.47 ? x ? 2.85. The observed decomposition temperature, determined from differential scanning calorimetry and thermogravimetry, is greater than 1000 \u00B0C in all cases and showed almost linear dependence on the iron content in the dodecahedral sites of the studied garnets, with the exception of garnet with a near-pyrope composition (Prp80Alm20). The initial garnet samples and decomposition products were characterized in details by means of X-ray powder diffraction and 57Fe M\u00F6ssbauer spectroscopy. We found that all studied garnets have common decomposition products such as metallic iron (in general, rounded particles below 4 m\u00FDm) and Fe-spinel; the other identified decomposition products depend on starting chemical composition of the garnet: Fe-cordierite, olivine (fayalite or tephroite), cristobalite, pyroxene (enstatite or pigeonite), and anorthite. Anorthite and pigeonite were only present in garnets with Ca in the dodecahedral site. All the identified phases were usually well crystallized." . . . "Filip, Jan" . "American Institute of Physics" . "Hlohovec u B\u0159eclavi" . "Ma\u0161l\u00E1\u0148, Miroslav" .