. "10.1016/j.poly.2011.08.022" . "Nickel(IV) dithiocarbamato complexes of the [Ni(ndtc)3]X type: X-ray structure of [Ni(hmidtc)3][FeCl4]" . "Peterek, Tom\u00E1\u0161" . "\u0160tarha, Pavel" . "Spectroscopy; X-ray structure; Dithiocarbamate; Nickel(IV) complexes"@en . . . "Polyhedron" . "Pastorek, Richard" . . . "Nickel(IV) dithiocarbamato complexes of the [Ni(ndtc)3]X type: X-ray structure of [Ni(hmidtc)3][FeCl4]"@en . "000296996500006" . . . . . . "Nickel(IV) dithiocarbamato complexes of the [Ni(ndtc)3]X type: X-ray structure of [Ni(hmidtc)3][FeCl4]" . . . . "17" . "6"^^ . "[12FBA96A74BB]" . "Tr\u00E1vn\u00ED\u010Dek, Zden\u011Bk" . "Fourteen octahedral Ni(IV) dithiocarbamato complexes of the general formula [Ni(ndtc)3]X.yH2O {ndtc stands for the appropriate dithiocarbamate anion, X stands for ClO4- (1-8; y = 0) or [FeCl4]- (9-14; y = 0 for 9-12, 1 for 13 and 0.5 for 14) was prepared by the oxidation of the corresponding Ni(II) complexes, i.e. [Ni(ndtc)2], with NOClO4 or FeCl3. The complexes, involving a high-valent Ni(IV)S6 core, were characterized by elemental analysis (C, H, N. Cl and Ni), UV-Vis and FTIR spectroscopy, thermal analysis and magnetochemical and conductivity measurements. The X-ray structure of {Ni(hmidtc)3][FeCl4] (9) was determined and this revealed slightly distorted octahedral and tetrahedral geometries within the complex cations, and anions, respectively. Moreover, the formal oxidation state of iron in (FeCl4]- as well as the coordination geometry in its vicinity was also proved by 57Fe Mossbauer spectroscopy in the case of 9."@en . . "RIV/61989592:15310/11:33116864" . . "0277-5387" . "30" . . . "Fourteen octahedral Ni(IV) dithiocarbamato complexes of the general formula [Ni(ndtc)3]X.yH2O {ndtc stands for the appropriate dithiocarbamate anion, X stands for ClO4- (1-8; y = 0) or [FeCl4]- (9-14; y = 0 for 9-12, 1 for 13 and 0.5 for 14) was prepared by the oxidation of the corresponding Ni(II) complexes, i.e. [Ni(ndtc)2], with NOClO4 or FeCl3. The complexes, involving a high-valent Ni(IV)S6 core, were characterized by elemental analysis (C, H, N. Cl and Ni), UV-Vis and FTIR spectroscopy, thermal analysis and magnetochemical and conductivity measurements. The X-ray structure of {Ni(hmidtc)3][FeCl4] (9) was determined and this revealed slightly distorted octahedral and tetrahedral geometries within the complex cations, and anions, respectively. Moreover, the formal oxidation state of iron in (FeCl4]- as well as the coordination geometry in its vicinity was also proved by 57Fe Mossbauer spectroscopy in the case of 9." . . . "RIV/61989592:15310/11:33116864!RIV13-MSM-15310___" . . "15310" . "216024" . "4"^^ . "Nickel(IV) dithiocarbamato complexes of the [Ni(ndtc)3]X type: X-ray structure of [Ni(hmidtc)3][FeCl4]"@en . . "3"^^ . "GB - Spojen\u00E9 kr\u00E1lovstv\u00ED Velk\u00E9 Brit\u00E1nie a Severn\u00EDho Irska" . . "P(ED2.1.00/03.0058), P(EE2.3.20.0017), Z(MSM6198959218)" .