. . . "10.1021/ic201702j" . "50" . "Tuning of the Critical Temperature in Iron(II) Spin-Crossover Materials Based on Bridging Polycyanidometallates: Pentacyanidonitrosylferrate(II) and Hexacyanidoplatinate(IV)"@en . "The reactions of iron(II) sulfate, 4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole (abpt), and pentacyanidonitrosylferrate(II) or hexacyanidoplatinate(IV) resulted in the formation of one-dimensional iron(II) spin-crossover compounds [Fe(abpt)2(u-Fe(CN)5(NO)]n (1) and [Fe(abpt)2(u-Pt(CN)6]n (2) with the spin-transition critical temperature near or above room temperature accompanied by thermochromism. Furthermore, it has been proven that the critical temperature Tc is influenced by the type of dianionic polycyanidometallate within the series of discussed systems, and it changes in the sequence of [Fe(CN)5(NO)](2-) { {Pt(CN)6](2-) { [Ni(CN)4](2-) approximate to [Pd(CN)4}(2-) approximate to [Pt(CN)4](2-)."@en . "Tuning of the Critical Temperature in Iron(II) Spin-Crossover Materials Based on Bridging Polycyanidometallates: Pentacyanidonitrosylferrate(II) and Hexacyanidoplatinate(IV)"@en . "3"^^ . "[D15BEC1815AF]" . "The reactions of iron(II) sulfate, 4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole (abpt), and pentacyanidonitrosylferrate(II) or hexacyanidoplatinate(IV) resulted in the formation of one-dimensional iron(II) spin-crossover compounds [Fe(abpt)2(u-Fe(CN)5(NO)]n (1) and [Fe(abpt)2(u-Pt(CN)6]n (2) with the spin-transition critical temperature near or above room temperature accompanied by thermochromism. Furthermore, it has been proven that the critical temperature Tc is influenced by the type of dianionic polycyanidometallate within the series of discussed systems, and it changes in the sequence of [Fe(CN)5(NO)](2-) { {Pt(CN)6](2-) { [Ni(CN)4](2-) approximate to [Pd(CN)4}(2-) approximate to [Pt(CN)4](2-)." . "3"^^ . "US - Spojen\u00E9 st\u00E1ty americk\u00E9" . "236211" . . "RIV/61989592:15310/11:33116857" . . "24" . . . . "3"^^ . . . . . . . "Zbo\u0159il, Radek" . . "Tuning of the Critical Temperature in Iron(II) Spin-Crossover Materials Based on Bridging Polycyanidometallates: Pentacyanidonitrosylferrate(II) and Hexacyanidoplatinate(IV)" . "Herchel, Radovan" . . "15310" . . "Tr\u00E1vn\u00ED\u010Dek, Zden\u011Bk" . . "Fe(II) complex, one-dimensional, spin crossover"@en . . "RIV/61989592:15310/11:33116857!RIV12-MSM-15310___" . "Inorganic Chemistry" . . "0020-1669" . . . "Tuning of the Critical Temperature in Iron(II) Spin-Crossover Materials Based on Bridging Polycyanidometallates: Pentacyanidonitrosylferrate(II) and Hexacyanidoplatinate(IV)" . "P(ED2.1.00/03.0058), P(EE2.3.20.0017), P(GAP207/11/0841), P(GP203/09/P370), P(KAN115600801)" .