. "Octahedral nickel(II) hexamethyleneimine-dithiocarbamato complexes involving bidentate N,N-donor ligands"@en . "Nickel(II) complexes, Hexamethyleneimine, Dithiocarbamate, X-ray structure"@en . "373" . . . . "The nickel(II) complexes of the compositions [Ni(hmidtc)(bpy)2]ClO4 (I), [Ni(hmidtc)(phen)2]ClO4 (II),[Ni(hmidtc)(phen)2]SCN (III), [Ni(hmidtc)(phen)2]PF6 (IV), [Ni(hmidtc)(phen)2]BPh4 (V), [Ni(hmidtc)(phen)2]AcO2H2O (VI) and [Ni(hmidtc)(phen)2]BrH2O (VII), involving a combination of one hexamethyleneimine-dithiocarbamate anion (hmidtc) and two bidentate N,N-donor ligands (2,20-bipyridine(bpy) for I or 1,10-phenanthroline (phen) for II-VII), have been prepared. The compounds were characterized by elemental analysis, molar conductivity measurements, UV-Vis and IR spectroscopy, magnetochemical measurements and thermal analysis. A single-crystal X-ray analysis of the complex I revealed a distorted octahedral geometry with the nickel(II) ion coordinated by four nitrogen atoms(from two bidentate-coordinated bpy molecules) and two sulfur atoms (from one bidentate-coordinated hmidtc anion), together giving an NiN4S2 donor set."@en . "15310" . "RIV/61989592:15310/11:10222340" . "000291244600042" . . "Octahedral nickel(II) hexamethyleneimine-dithiocarbamato complexes involving bidentate N,N-donor ligands" . . . "[534AC810F6E8]" . . . . . . "Octahedral nickel(II) hexamethyleneimine-dithiocarbamato complexes involving bidentate N,N-donor ligands" . "Inorganica Chimica Acta" . "P(ED2.1.00/03.0058), Z(MSM6198959218)" . "Octahedral nickel(II) hexamethyleneimine-dithiocarbamato complexes involving bidentate N,N-donor ligands"@en . "NL - Nizozemsko" . "\u0160tarha, Pavel" . . . "Pastorek, Richard" . "5"^^ . . "217535" . "3"^^ . . "RIV/61989592:15310/11:10222340!RIV12-MSM-15310___" . . "Tr\u00E1vn\u00ED\u010Dek, Zden\u011Bk" . "1" . "0020-1693" . "The nickel(II) complexes of the compositions [Ni(hmidtc)(bpy)2]ClO4 (I), [Ni(hmidtc)(phen)2]ClO4 (II),[Ni(hmidtc)(phen)2]SCN (III), [Ni(hmidtc)(phen)2]PF6 (IV), [Ni(hmidtc)(phen)2]BPh4 (V), [Ni(hmidtc)(phen)2]AcO2H2O (VI) and [Ni(hmidtc)(phen)2]BrH2O (VII), involving a combination of one hexamethyleneimine-dithiocarbamate anion (hmidtc) and two bidentate N,N-donor ligands (2,20-bipyridine(bpy) for I or 1,10-phenanthroline (phen) for II-VII), have been prepared. The compounds were characterized by elemental analysis, molar conductivity measurements, UV-Vis and IR spectroscopy, magnetochemical measurements and thermal analysis. A single-crystal X-ray analysis of the complex I revealed a distorted octahedral geometry with the nickel(II) ion coordinated by four nitrogen atoms(from two bidentate-coordinated bpy molecules) and two sulfur atoms (from one bidentate-coordinated hmidtc anion), together giving an NiN4S2 donor set." . . "3"^^ . . . .