"Applicability of the previously described rearrangement of 2-oxo-2-phenylethyl 2-amino?benzoate leading to 2-phenyl-2-hydroxymethyl-2,3-dihydroquinazolin-4(1H)-one has been studied. To test the limits of the reaction, various starting compounds such as 2-oxopropyl 2-aminobenzoate, 2-oxo-2-phenylethyl 2-aminobenzoate and 3,3-dimethyl-2-oxobutyl 2-aminobenzoate as well as some of their corresponding N-methyl and N-phenyl analogues were used. The structure-reactivity dependence was observed giving the expected products only in specific cases and in limited yields. Structure of the dihydroquinazolin-4(1H)-one skeleton was unambiguously confirmed with use of X-ray analysis of two selected compounds. Finally, an alternative way for the preparation of the desired derivatives was developed." . "US - Spojen\u00E9 st\u00E1ty americk\u00E9" . . "P(ME09057), Z(MSM6198959216)" . "Arkivoc" . . "6"^^ . . "1424-6376" . "Study of anthranilate cyclisation to 2-hydroxymethyl-2,3-dihydro-quinazolin-4(1H)-ones and an alternative synthetic route" . . "Dihydroquinazolinone, rearrangement, X-ray, condensation"@en . "Soural, Miroslav" . . . "Funk, Petr" . . . . . "RIV/61989592:15310/10:10215446" . "Kvapil, L." . "10" . . . "Applicability of the previously described rearrangement of 2-oxo-2-phenylethyl 2-amino?benzoate leading to 2-phenyl-2-hydroxymethyl-2,3-dihydroquinazolin-4(1H)-one has been studied. To test the limits of the reaction, various starting compounds such as 2-oxopropyl 2-aminobenzoate, 2-oxo-2-phenylethyl 2-aminobenzoate and 3,3-dimethyl-2-oxobutyl 2-aminobenzoate as well as some of their corresponding N-methyl and N-phenyl analogues were used. The structure-reactivity dependence was observed giving the expected products only in specific cases and in limited yields. Structure of the dihydroquinazolin-4(1H)-one skeleton was unambiguously confirmed with use of X-ray analysis of two selected compounds. Finally, an alternative way for the preparation of the desired derivatives was developed."@en . . . "Study of anthranilate cyclisation to 2-hydroxymethyl-2,3-dihydro-quinazolin-4(1H)-ones and an alternative synthetic route" . "Hradil, Pavel" . . "RIV/61989592:15310/10:10215446!RIV11-MSM-15310___" . "15310" . . "[D07B777498A5]" . "Study of anthranilate cyclisation to 2-hydroxymethyl-2,3-dihydro-quinazolin-4(1H)-ones and an alternative synthetic route"@en . . "11"^^ . "Hlav\u00E1\u010D, Jan" . . "290731" . . "NA" . "4"^^ . "Study of anthranilate cyclisation to 2-hydroxymethyl-2,3-dihydro-quinazolin-4(1H)-ones and an alternative synthetic route"@en . . "Bertolasi, V." . "000282480400021" . .