. . . . "RIV/61989592:15310/07:00005816" . "RIV/61989592:15310/07:00005816!RIV10-MSM-15310___" . "0173-0835" . "Hor\u00E1kov\u00E1, Hana" . . "Cluster anions of boron are built up on three-center two-electron bonds in contrast to naturally occurring compounds and their synthetic analogs. Methanol works as a solvent and as a competing agent, which advantageously adjusts reasonable strength of their interaction with native CDs in water-organic BGE. The highest methanol concentration preserving chiral discrimination of atropoisomers of individual anions is approximately 35, 55 and 75% v/v for -, - and -CD, respectively. -CD separates anionic 7, 8-nido-dicarbaundecaborate clusters with small exo-skeletal substituents. -CD separates anions of all four tested structural types. The efficiency of separation of a compound with - or -CD is always markedly lower than the separation efficiency at the absence of a CD in BGE. The efficiency of separation of a compound with -CD is always lower than the efficiency of separation of the compound with -CD. -CD was proved to be unsuitable as a chiral selector because in BGEs with -CD, effective mobilities of an"@en . . . "P(IAA400310613), S, Z(AV0Z40310501), Z(MSM6198959216)" . . . "11"^^ . "[675B4466EBCD]" . . "Electrophoresis" . "Vespalec, Radim" . . "Chiral separability of hydrophobic boron cluster anions with native cyclodextrins in water-methanol background electrolytes" . "2"^^ . "413521" . "15310" . "1"^^ . "Cluster anions of boron are built up on three-center two-electron bonds in contrast to naturally occurring compounds and their synthetic analogs. Methanol works as a solvent and as a competing agent, which advantageously adjusts reasonable strength of their interaction with native CDs in water-organic BGE. The highest methanol concentration preserving chiral discrimination of atropoisomers of individual anions is approximately 35, 55 and 75% v/v for -, - and -CD, respectively. -CD separates anionic 7, 8-nido-dicarbaundecaborate clusters with small exo-skeletal substituents. -CD separates anions of all four tested structural types. The efficiency of separation of a compound with - or -CD is always markedly lower than the separation efficiency at the absence of a CD in BGE. The efficiency of separation of a compound with -CD is always lower than the efficiency of separation of the compound with -CD. -CD was proved to be unsuitable as a chiral selector because in BGEs with -CD, effective mobilities of an" . . . "28" . "20" . . . . "DE - Spolkov\u00E1 republika N\u011Bmecko" . "Chiral separability of hydrophobic boron cluster anions with native cyclodextrins in water-methanol background electrolytes"@en . . . "Chiral separability of hydrophobic boron cluster anions with native cyclodextrins in water-methanol background electrolytes"@en . "Chiral separability of hydrophobic boron cluster anions with native cyclodextrins in water-methanol background electrolytes" . . . "Boron cluster compound; CE; Chiral separation; Cyclodextrin; Mixed solvent"@en . .