. "6"^^ . . . "23" . "4"^^ . "Marek, Jarom\u00EDr" . "0277-5387" . "RIV/61989592:15310/04:00009894!RIV10-MSM-15310___" . . "9" . . "Tr\u00E1vn\u00ED\u010Dek, Zden\u011Bk" . "Syntheses and study on nickel(II) complexes with thiodiglycolic acid and nitrogen-donor ligands. X-ray structures of [Ni(bpy)(tdga)(H2O)].4H2O and [(en)Ni(mu-tdga)2Ni(en)].4H2O (tdgaH2 = thiodiglycolic acid)"@en . . "nickel(II); thiodiglycolic acid complexes; X-ray complexes; magnetic properties"@en . . . "GB - Spojen\u00E9 kr\u00E1lovstv\u00ED Velk\u00E9 Brit\u00E1nie a Severn\u00EDho Irska" . . "Mixed-ligand Ni(II) complexes involving thioglycolate(2-) (tdga) and nitrogen-donor ligands in the coordination sphere have been prepared. The complexes of composition [Ni(bpy)(tdga)(H2O)].4H2O (1), [(en)Ni(mu-tdga)(2)Ni(en)].4H2O (2), [Ni(phen)(tdga)(H2O)].H2O (3), [Ni(1,8-dan)(tdga)(H2O)] (4), [Ni(nphen)(tdga)(H2O)].H2O (5), [Ni(ampy)(tdga)(H2O)] (6), where bpy = 2,2'-bipyridine, en = ethylenediamine, phen = 1,10-phenanthroline, 1,8-dan = 1,8-diaminonaphthalene, nphen = 5-nitro-1,10-phenanthroline and ampy = 2-(aminomethyl)-pyridine, have been characterized by elemental analysis, IR and UV-VIS spectroscopies, and magnetic susceptibility measurements. Room temperature effective magnetic moments for 1-6 are ranging from 3.06 to 3.28 mu(eff)/mu(B) and thus indicating that nickel atoms are six-coordinated in a deformed octahedral arrangement in all the prepared complexes. This conclusion has been confirmed by single-crystal X-ray analysis of [Ni(bpy)(tdga)(H2O)].4H2O (1). A binuclear structure of c"@en . "Syntheses and study on nickel(II) complexes with thiodiglycolic acid and nitrogen-donor ligands. X-ray structures of [Ni(bpy)(tdga)(H2O)].4H2O and [(en)Ni(mu-tdga)2Ni(en)].4H2O (tdgaH2 = thiodiglycolic acid)"@en . "Polyhedron" . . "Mrozi\u0144ski, Jerzy" . . "Mixed-ligand Ni(II) complexes involving thioglycolate(2-) (tdga) and nitrogen-donor ligands in the coordination sphere have been prepared. The complexes of composition [Ni(bpy)(tdga)(H2O)].4H2O (1), [(en)Ni(mu-tdga)(2)Ni(en)].4H2O (2), [Ni(phen)(tdga)(H2O)].H2O (3), [Ni(1,8-dan)(tdga)(H2O)] (4), [Ni(nphen)(tdga)(H2O)].H2O (5), [Ni(ampy)(tdga)(H2O)] (6), where bpy = 2,2'-bipyridine, en = ethylenediamine, phen = 1,10-phenanthroline, 1,8-dan = 1,8-diaminonaphthalene, nphen = 5-nitro-1,10-phenanthroline and ampy = 2-(aminomethyl)-pyridine, have been characterized by elemental analysis, IR and UV-VIS spectroscopies, and magnetic susceptibility measurements. Room temperature effective magnetic moments for 1-6 are ranging from 3.06 to 3.28 mu(eff)/mu(B) and thus indicating that nickel atoms are six-coordinated in a deformed octahedral arrangement in all the prepared complexes. This conclusion has been confirmed by single-crystal X-ray analysis of [Ni(bpy)(tdga)(H2O)].4H2O (1). A binuclear structure of c" . "Syntheses and study on nickel(II) complexes with thiodiglycolic acid and nitrogen-donor ligands. X-ray structures of [Ni(bpy)(tdga)(H2O)].4H2O and [(en)Ni(mu-tdga)2Ni(en)].4H2O (tdgaH2 = thiodiglycolic acid)" . "Kopel, Pavel" . . . . . . "RIV/61989592:15310/04:00009894" . . "[72FD444E5200]" . "15310" . "P(GA203/02/0436), Z(MSM 143100008), Z(MSM 153100007)" . . "Syntheses and study on nickel(II) complexes with thiodiglycolic acid and nitrogen-donor ligands. X-ray structures of [Ni(bpy)(tdga)(H2O)].4H2O and [(en)Ni(mu-tdga)2Ni(en)].4H2O (tdgaH2 = thiodiglycolic acid)" . . "2"^^ . "589308" . .