. "Struktura pentakoordinovan\u00E9ho komplexu s NiS4Sb chromoforem"@cs . . "nickel(II) complexes;S-ligands;Sb-ligands;X-ray structure"@en . . "Z(MSM 153100007)" . "RIV/61989592:15310/04:00002136!RIV/2005/MSM/153105/N" . "588573" . . "V r\u00E1mci systematick\u00E9ho studia dithiokarbam\u00E1tov\u00FDch komplex\u016F niklu(II) byly na na\u0161em pracovi\u0161ti studov\u00E1ny komplexy studov\u00E1ny komplexy s obvykl\u00FDm koordina\u010Dn\u00EDm \u010D\u00EDslem \u010Dty\u0159i (chromofor NiS4, NiS2PX, X = Cl, Br, NiS2P2) i s rovn\u011B\u017E obvykl\u00FDm koordian\u010Dn\u00EDm \u010D\u00EDslem \u0161est (chromofor NiS2N4). V posledn\u00ED dob\u011B jsme syntetizovali n\u011Bkolik l\u00E1tek s neobvykl\u00FDm koordina\u010Dn\u00EDm \u010D\u00EDslem p\u011Bt u centr\u00E1ln\u00EDho atomu. Jedn\u00EDm z p\u0159\u00EDklad\u016F, kdy se poda\u0159ilo z\u00EDskat i krystaly vhodn\u00E9 pro kompletn\u00ED rentgenostrukturn\u00ED anal\u00FDzu, byl komplex o slo\u017Een\u00ED NiC30H28N2S4Sb.CS2. Bylo prok\u00E1z\u00E1no, \u017Ee studovan\u00FD komplex skute\u010Dn\u011B obsahuje chromofor NiS4Sb (m\u00EDrn\u011B deformovan\u00E1 tetragon\u00E1ln\u00ED pyramida), p\u0159i\u010Dem\u017E d\u00E9lky vazeb Ni1-S se pohybuj\u00ED od 2.199 do 2.221 A a u Ni1-Sb1 2.934 A. Ve struktu\u0159e se nach\u00E1z\u00ED 1 molekula sirouhl\u00EDku jako krystalosolv\u00E1t."@cs . "Struktura pentakoordinovan\u00E9ho komplexu s NiS4Sb chromoforem" . "15310" . "497" . . "V r\u00E1mci systematick\u00E9ho studia dithiokarbam\u00E1tov\u00FDch komplex\u016F niklu(II) byly na na\u0161em pracovi\u0161ti studov\u00E1ny komplexy studov\u00E1ny komplexy s obvykl\u00FDm koordina\u010Dn\u00EDm \u010D\u00EDslem \u010Dty\u0159i (chromofor NiS4, NiS2PX, X = Cl, Br, NiS2P2) i s rovn\u011B\u017E obvykl\u00FDm koordian\u010Dn\u00EDm \u010D\u00EDslem \u0161est (chromofor NiS2N4). V posledn\u00ED dob\u011B jsme syntetizovali n\u011Bkolik l\u00E1tek s neobvykl\u00FDm koordina\u010Dn\u00EDm \u010D\u00EDslem p\u011Bt u centr\u00E1ln\u00EDho atomu. Jedn\u00EDm z p\u0159\u00EDklad\u016F, kdy se poda\u0159ilo z\u00EDskat i krystaly vhodn\u00E9 pro kompletn\u00ED rentgenostrukturn\u00ED anal\u00FDzu, byl komplex o slo\u017Een\u00ED NiC30H28N2S4Sb.CS2. Bylo prok\u00E1z\u00E1no, \u017Ee studovan\u00FD komplex skute\u010Dn\u011B obsahuje chromofor NiS4Sb (m\u00EDrn\u011B deformovan\u00E1 tetragon\u00E1ln\u00ED pyramida), p\u0159i\u010Dem\u017E d\u00E9lky vazeb Ni1-S se pohybuj\u00ED od 2.199 do 2.221 A a u Ni1-Sb1 2.934 A. Ve struktu\u0159e se nach\u00E1z\u00ED 1 molekula sirouhl\u00EDku jako krystalosolv\u00E1t." . "The structure of pentacoordinated complex with NiS4Sb chromophore"@en . "The structure of pentacoordinated complex with NiS4Sb chromophore"@en . "8" . "0009-2770" . "3"^^ . . . "In the scope of the systematic study of nickel(II) dithiocarbamates have been studied complexes with an usual coordination number four (chromophore NiS4, NiS2PX, X = Cl, Br, NiS2P2) as well with an usual coordination number six (chromophore NiS2N4) in our department. We have synthesized compounds with unusual coordination number five of the central atom in last time. At one example, the crystals suitable for the complete rentgenostructural analysis were obtained(NiC30H28N2S4Sb.CS2). It was found, that the studied complex really contains the chromophore NiS4Sb (slightly deformed tetragonal pyramid) with the bond lengths Ni1-S from 2.199 to 2.221 A and Ni1-Sb 2.934 A. One molecule of carbondisulfide is as crystalosolvate at this structure."@en . "98" . . "[CCF3DA0514B7]" . "1"^^ . "Struktura pentakoordinovan\u00E9ho komplexu s NiS4Sb chromoforem"@cs . "Chemick\u00E9 listy" . "4"^^ . "Pastorek, Richard" . . . . . "Struktura pentakoordinovan\u00E9ho komplexu s NiS4Sb chromoforem" . "Kamen\u00ED\u010Dek, Ji\u0159\u00ED" . "RIV/61989592:15310/04:00002136" . . "Tr\u00E1vn\u00ED\u010Dek, Zden\u011Bk" . . . . "Cvek, Boris" . . . "CZ - \u010Cesk\u00E1 republika" .