"Masarykova univerzita. P\u0159\u00EDrodov\u011Bdeck\u00E1 fakulta. Katedra anorganick\u00E9 chemie" . . . . . "\u0160indel\u00E1\u0159, Zden\u011Bk" . "C\u00EDlem pr\u00E1ce bylo p\u0159ipravit komplexn\u00ED slou\u010Deniny obsahuj\u00EDc\u00ED jako centr\u00E1ln\u00ED atom nikl v oxida\u010Dn\u00EDm stavu II a jako ligandy dithiokarbam\u00E1tov\u00E9 anionty. V\u00FDchoz\u00ED dithiokarbam\u00E1ty [Ni(R2dtc)2] (R = pentyl, benzyl; dtc = S2CN#) byly p\u0159ipraveny reakc\u00ED CS2 s p\u0159\u00EDslu\u0161n\u00FDm aminem (R2NH) v ethanolu a p\u0159id\u00E1n\u00EDm roztoku NiCl2#6H2O ve vod\u011B. Sm\u00EDch\u00E1n\u00EDm [Ni(R2dtc)2] s [NiX2(PR\u00B43)2] [2] v CHCl3 (X = Cl#, Br#, I#, NCS#; R\u00B4 = fenyl, butyl) v pom\u011Bru 1:1 vznikly fialov\u00E9 diamagnetick\u00E9 komplexy o slo\u017Een\u00ED [NiX(R2dtc)(PR\u00B43)]. \u010Cerveno-oran\u017Eov\u00E9 diamagnetick\u00E9 l\u00E1tky typu [Ni(R2dtc)(PR\u00B43)2]Y (Y = ClO4#, PF6#) byly p\u0159ipraveny reakc\u00ED [Ni(R2dtc)2] a PR\u00B43 v pom\u011Bru 1:1 v CH3OH. Suspenze byla za m\u00EDch\u00E1n\u00ED 1 hodinu refluxov\u00E1na, pak byl p\u0159id\u00E1n LiClO4 .3H2O, resp. K[PF6] . Poda\u0159ilo se izolovat celkem23 nov\u00FDch l\u00E1tek (v\u010Detn\u011B dvou v\u00FDchoz\u00EDch komplex\u016F), kter\u00E9 byly bl\u00ED\u017Ee studov\u00E1ny pomoc\u00ED magnetochemick\u00FDch m\u011B\u0159en\u00ED, termick\u00E9 anal\u00FDzy, IR a UV/VIS spekter a mol\u00E1rn\u00ED vodivosti. komplex\u016F. U [NiI(dpdtc)(PPh3)] a [Ni(dpdtc)(PPh3)2]ClO4 byla provedena RTG-anal\u00FDza." . "Z(MSM 153100007)" . . "Nickel II dipentyldithiocarbamates; dibenzyldithiocarbamates"@en . . "Ni(II)-dipentyl-, resp.dibenzyldithiokarbam\u00E1ty"@cs . "26-27" . "RIV/61989592:15310/02:00001443!RIV/2003/MSM/153103/N" . "Brno" . . . "Synthesis and study of the coordination compounds derived from nickel II cyklohexylethyldithiokarbamate"@en . . "Ni(II)-dipentyl-, resp.dibenzyldithiokarbam\u00E1ty" . "0"^^ . "4"^^ . "Ni(II)-dipentyl-, resp.dibenzyldithiokarbam\u00E1ty"@cs . "Pastorek, Richard" . "[C1E2868BE09D]" . "0"^^ . . "3"^^ . "72"^^ . "80-210-2951-X" . "Cvek, Boris" . "Synthesis and study of the coordination compounds derived from nickel II cyklohexylethyldithiokarbamate"@en . "15310" . . . "Ni(II)-dipentyl-, resp.dibenzyldithiokarbam\u00E1ty" . . "Vranov u Brna" . "655662" . "The aim of this work was to prepare Ni(II) coordination compounds with dithiocarbamate anions as ligands. The dithiocarbamates [Ni(R2dtc)2] (R = pentyl, benzyl; dtc = S2CN#) were prepared by the reaction of CS2 with corresponding amine (R2NH) in ethanol and by subsequent addition of NiCl2 aqueous solution into the reaction mixture. [Ni(R2dtc)2] compounds were used as a starting material for the following synteses: By mixing of [Ni(R2dtc)2] with [NiX2(PR\u00B43)2] [2] in CHCl3 (X = Cl#, Br#, I#, NCS#; R\u00B4 = fenyl, butyl) in 1:1 ratio violet diamagnetic complexes [NiX(R2dtc)(PR\u00B43)] were prepared. Reddish - orange compounds [Ni(R2dtc)(PR\u00B43)2]Y (Y = ClO4#, PF6#) were formed by the reaction of [Ni(R2dtc)2] and PR\u00B43 (1:1 ratio) in CH3OH (1 hour reflux followed byaddition of LiClO4 .3H2O or K[PF6] resp.). 23 novel compounds were isolated and studied using magnetochemical methods, thermal analysis, IR/UV/VIS spectra and conductometry. Rentgenostructural analysis was completed in the case of [NiI(dpdtc)(PPh3)] an"@en . "RIV/61989592:15310/02:00001443" . . . . "Kamen\u00ED\u010Dek, Ji\u0159\u00ED" . . "IV. Semin\u00E1\u0159: %22Pokroky v anorganick\u00E9 chemii%22" .