"Murali, A." . . . "3"^^ . "13" . "Single-electron transfer living radical copolymerization of SWCNT-g-PMMA via graft from approach" . . "I, P(GAP108/12/1459)" . "Single-electron transfer living radical copolymerization of SWCNT-g-PMMA via graft from approach" . . . "0032-3861" . "Single-electron transfer living radical copolymerization of SWCNT-g-PMMA via graft from approach"@en . "Ponyrko, Sergii" . . "10.1016/j.polymer.2014.04.054" . "Single-electron transfer living radical copolymerization of SWCNT-g-PMMA via graft from approach"@en . "55" . . . "RIV/61389013:_____/14:00428660!RIV15-GA0-61389013" . . "single electron transfer; single-walled carbon nanotubes; controlled radical polymerization"@en . . "Mandal, A. B." . "Haridharan, N." . "[E783A8EFF50A]" . "Jaisankar, S. N." . . . . "45084" . "000337549000004" . "Ponyrko, Sergii" . "8"^^ . "\u0160p\u00EDrkov\u00E1, Milena" . "The sidewall functionalization of single-walled carbon nanotubes (SWCNTs) was established by poly(methyl methacrylate) (PMMA) using controlled radical polymerization (CRP) method. A bromide functionalized SWCNT (SWCNT-Br) has been used as an initiator for the synthesis of SWCNT-graft-PMMA (SWCNT-g-PMMA). The efficiency of the sacrificial initiator (S) was monitored during the polymerization process. The obtained polymers possess a uniform distribution of molecular weight with a lower polydispersity index of 1.36. The SWCNTs-based initiator acts as an efficient medium for the controlled growth of polymer on the SWCNTs surfaces. The presence of bimodal gel permeation chromatographic (GPC) curve for the SWCNT-g-PMMA(S) obtained through sacrificial initiator (S) confirms uncontrolled behavior. However, the clear sharp peak for SWCNT-g-PMMA obtained without sacrificial initiator shows its well-controlled process of polymerization, which acts as a mimic to bone cement. The efficiency of the functionalization of SWCNT and the controlled formation of SWCNT-g-PMMA composites were characterized by TGA, Raman, TEM, NMR, XPS and dispersion measurements." . "7"^^ . "Polymer" . "GB - Spojen\u00E9 kr\u00E1lovstv\u00ED Velk\u00E9 Brit\u00E1nie a Severn\u00EDho Irska" . "Mat\u011Bjka, Libor" . "RIV/61389013:_____/14:00428660" . . . "The sidewall functionalization of single-walled carbon nanotubes (SWCNTs) was established by poly(methyl methacrylate) (PMMA) using controlled radical polymerization (CRP) method. A bromide functionalized SWCNT (SWCNT-Br) has been used as an initiator for the synthesis of SWCNT-graft-PMMA (SWCNT-g-PMMA). The efficiency of the sacrificial initiator (S) was monitored during the polymerization process. The obtained polymers possess a uniform distribution of molecular weight with a lower polydispersity index of 1.36. The SWCNTs-based initiator acts as an efficient medium for the controlled growth of polymer on the SWCNTs surfaces. The presence of bimodal gel permeation chromatographic (GPC) curve for the SWCNT-g-PMMA(S) obtained through sacrificial initiator (S) confirms uncontrolled behavior. However, the clear sharp peak for SWCNT-g-PMMA obtained without sacrificial initiator shows its well-controlled process of polymerization, which acts as a mimic to bone cement. The efficiency of the functionalization of SWCNT and the controlled formation of SWCNT-g-PMMA composites were characterized by TGA, Raman, TEM, NMR, XPS and dispersion measurements."@en . . .