"Macromolecules" . "Synthesis of well-defined semitelechelic poly[N-(2-hydroxypropyl)methacrylamide] polymers with functional group at the .alpha.-end of the polymer chain by RAFT polymerization" . . "Ulbrich, Karel" . "\u0160ubr, Vladim\u00EDr" . "109558" . . . "0024-9297" . . "000316847500007" . "6" . . "Synthesis of well-defined semitelechelic poly[N-(2-hydroxypropyl)methacrylamide] polymers with functional group at the .alpha.-end of the polymer chain by RAFT polymerization"@en . . "46" . . "10.1021/ma400042u" . "Etrych, Tom\u00E1\u0161" . . "[25D627792AE1]" . . "N-(2-Hydroxypropyl)methacrylamide polymer precursors (pHPMA) with very narrow distribution of molecular weights and polymer chain terminating in a single reactive group have big potential in the synthesis of various polymer drug and gene delivery systems. This paper shows that pHPMA can be prepared by reversible addition-fragmentation chain transfer (RAFT) polymerization; the pHPMAs prepared by RAFT polymerization conducted to high conversions contained at the \u03B1-end of the polymer chain a single functional group originated from both, the chain transfer agent (CTA) and initiator (INI) in ratio depending on polymerization conditions. The well-defined monofunctional pHPMAs with narrow molecular weight distribution and with single reactive group situated at the \u03B1-polymer chain end can be prepared in one step by RAFT polymerization initiated by the tailor-made CTA and INI, both containing the same functional group in their structure. Synthesis of pHPMAs terminating in various reactive groups (azide, propargyl, thiazolidin-2-thione, amino, hydrazide) was also described." . "RIV/61389013:_____/13:00391498!RIV14-MSM-61389013" . . "Kostka, Libor" . . . . "5"^^ . "RAFT polymerization; N-(2-hydroxypropyl)methacrylamide; semitelechelic polymers"@en . . . "US - Spojen\u00E9 st\u00E1ty americk\u00E9" . "5"^^ . . "RIV/61389013:_____/13:00391498" . . "9"^^ . "Synthesis of well-defined semitelechelic poly[N-(2-hydroxypropyl)methacrylamide] polymers with functional group at the .alpha.-end of the polymer chain by RAFT polymerization" . . . . "Strohalm, Ji\u0159\u00ED" . "N-(2-Hydroxypropyl)methacrylamide polymer precursors (pHPMA) with very narrow distribution of molecular weights and polymer chain terminating in a single reactive group have big potential in the synthesis of various polymer drug and gene delivery systems. This paper shows that pHPMA can be prepared by reversible addition-fragmentation chain transfer (RAFT) polymerization; the pHPMAs prepared by RAFT polymerization conducted to high conversions contained at the \u03B1-end of the polymer chain a single functional group originated from both, the chain transfer agent (CTA) and initiator (INI) in ratio depending on polymerization conditions. The well-defined monofunctional pHPMAs with narrow molecular weight distribution and with single reactive group situated at the \u03B1-polymer chain end can be prepared in one step by RAFT polymerization initiated by the tailor-made CTA and INI, both containing the same functional group in their structure. Synthesis of pHPMAs terminating in various reactive groups (azide, propargyl, thiazolidin-2-thione, amino, hydrazide) was also described."@en . . . "Synthesis of well-defined semitelechelic poly[N-(2-hydroxypropyl)methacrylamide] polymers with functional group at the .alpha.-end of the polymer chain by RAFT polymerization"@en . "I, P(EE2.3.30.0029), P(GAP301/12/1254)" .