"258244" . "0022-2860" . "The stability constant of the complex of hexaarylbenzene (HAB) - based receptor and ammonium cation in nitrobenzene saturated with water was determined from extraction experiments and gamma-activity measurements. Further, using quantum chemical DFT calculations, two most probable structures of the studied complex species, which are obviously in a dynamic equilibrium, were indicated. In both of these structures of the resulting complex, having C_3 symmetry, the ammonium cation synergistically interacts with the polar ethereal oxygen fence and with the central hydrophobic benzene bottom via cation-pi interaction."@en . "Experimental and DFT study on the complexation of NH4+ with a hexaarylbenzene-based receptor"@en . . "P(GAP205/10/2280), S, Z(AV0Z40500505), Z(MSM4977751303)" . . . "extraction; DFT; complexation"@en . . "Journal of Molecular Structure" . . "Seluck\u00FD, P." . "The stability constant of the complex of hexaarylbenzene (HAB) - based receptor and ammonium cation in nitrobenzene saturated with water was determined from extraction experiments and gamma-activity measurements. Further, using quantum chemical DFT calculations, two most probable structures of the studied complex species, which are obviously in a dynamic equilibrium, were indicated. In both of these structures of the resulting complex, having C_3 symmetry, the ammonium cation synergistically interacts with the polar ethereal oxygen fence and with the central hydrophobic benzene bottom via cation-pi interaction." . . "4"^^ . "[506584DAA3F5]" . "Va\u0148ura, P." . "5"^^ . . "977" . "Makrl\u00EDk, E." . "Experimental and DFT study on the complexation of NH4+ with a hexaarylbenzene-based receptor" . "Experimental and DFT study on the complexation of NH4+ with a hexaarylbenzene-based receptor" . . . "Experimental and DFT study on the complexation of NH4+ with a hexaarylbenzene-based receptor"@en . . . "1"^^ . . "NL - Nizozemsko" . "RIV/61389013:_____/10:00346358!RIV11-GA0-61389013" . . . "RIV/61389013:_____/10:00346358" . . . . "1-3" . . . "Rathore, R." . "000280498600035" . "Toman, Petr" .