. . "DE - Spolkov\u00E1 republika N\u011Bmecko" . "Experimental and DFT study on the complexation of Zn2+ with valinomycin"@en . "From extraction experiments and gamma-activity measurements, the exchange extraction constant corresponding to the equilibrium Zn2+(aq) + 1.Sr2+(nb) equil. 1.Zn2+(nb) + Sr2+(aq) in the two-phase water (aq) \u2013 nitrobenzene (nb) system (1: valinomycin) was evaluated as -0.2 +/- 0.1. By using quantum mechanical DFT calculations, the most probable structure of the 1.Zn2+ complex species was predicted with the cation in the center of the coordination cavity formed by six ester carbonyls and binding energy of 359.5 kcal/mol." . . "From extraction experiments and gamma-activity measurements, the exchange extraction constant corresponding to the equilibrium Zn2+(aq) + 1.Sr2+(nb) equil. 1.Zn2+(nb) + Sr2+(aq) in the two-phase water (aq) \u2013 nitrobenzene (nb) system (1: valinomycin) was evaluated as -0.2 +/- 0.1. By using quantum mechanical DFT calculations, the most probable structure of the 1.Zn2+ complex species was predicted with the cation in the center of the coordination cavity formed by six ester carbonyls and binding energy of 359.5 kcal/mol."@en . "[2D3E5F8D4195]" . . "P(1ET400500402), Z(AV0Z40500505)" . "8" . . . "314191" . . "Experimental and DFT study on the complexation of Zn2+ with valinomycin" . "Zeitschrift f\u00FCr Kristallographie" . . "7"^^ . "Experimental and DFT study on the complexation of Zn2+ with valinomycin" . . "Dybal, Ji\u0159\u00ED" . . "0044-2968" . "Experimental and DFT study on the complexation of Zn2+ with valinomycin"@en . "Va\u0148ura, P." . "1"^^ . "Makrl\u00EDk, E." . . "3"^^ . "RIV/61389013:_____/09:00330992" . . "000270615600005" . . "RIV/61389013:_____/09:00330992!RIV10-AV0-61389013" . "valinomycin; zinc; complexation"@en . . . "223" . . .