"[79E0E8912FAF]" . "A set of four water-soluble (3-methoxypropyl)stannanes of general formula (CH3OCH2CH2CH2)(x)SnCl4-x, where x = 4 (1), x = 3 (2), x = 2 (3), and x = 1 (4), was prepared. For 3 and 4, which were isolated in the crystalline state, it was shown by X-ray diffraction that the tin atom is coordinated in distorted octahedral and trigonal-bipyramidal geometries, respectively (i.e., the oxygen atoms of the 3-methoxypropyl groups were coordinated to the central tin atom in both cases, forming chelates). For all compounds, structures in CDCl3 and [D-6]DMSO solutions were proposed on the basis of their C-13 and Sn-119 NMR spectra. In CDCl3 solution, the degree of donor-acceptor bonding between the central tin atom and oxygen atom of the 3-methoxypropyl substituent was evaluated on the basis of O-17 NMR chemical shifts and 3,6J(H-1,Sn-119) long-range coupling constants. Compounds 2 and 3 exhibited promising antitumour and trypanocidal activities in vitro."@en . . "1"^^ . . . "1434-1948" . . "0"^^ . "4"^^ . "N/A" . "0"^^ . . . . "1" . "P(LN00A028), Z(AV0Z4050913)" . "RIV/61389013:_____/03:55033007!RIV/2004/AV0/A55004/N" . "tin; chelates; O ligands"@en . "Synthesis, structural study, and in vitro trypanocidal and antitumour activities of tetrakis(3-methoxypropyl)tin and (3-methoxypropyl)tin chlorides."@en . . "6"^^ . "143;148" . . . "Synthesis, structural study, and in vitro trypanocidal and antitumour activities of tetrakis(3-methoxypropyl)tin and (3-methoxypropyl)tin chlorides." . . "RIV/61389013:_____/03:55033007" . . "Smi\u010Dka, A." . . "L\u00E9bl, T." . . "European Journal of Inorganic Chemistry" . "Bruhn, C." . "Synthesis, structural study, and in vitro trypanocidal and antitumour activities of tetrakis(3-methoxypropyl)tin and (3-methoxypropyl)tin chlorides."@en . . . "A set of four water-soluble (3-methoxypropyl)stannanes of general formula (CH3OCH2CH2CH2)(x)SnCl4-x, where x = 4 (1), x = 3 (2), x = 2 (3), and x = 1 (4), was prepared. For 3 and 4, which were isolated in the crystalline state, it was shown by X-ray diffraction that the tin atom is coordinated in distorted octahedral and trigonal-bipyramidal geometries, respectively (i.e., the oxygen atoms of the 3-methoxypropyl groups were coordinated to the central tin atom in both cases, forming chelates). For all compounds, structures in CDCl3 and [D-6]DMSO solutions were proposed on the basis of their C-13 and Sn-119 NMR spectra. In CDCl3 solution, the degree of donor-acceptor bonding between the central tin atom and oxygen atom of the 3-methoxypropyl substituent was evaluated on the basis of O-17 NMR chemical shifts and 3,6J(H-1,Sn-119) long-range coupling constants. Compounds 2 and 3 exhibited promising antitumour and trypanocidal activities in vitro." . "DE - Spolkov\u00E1 republika N\u011Bmecko" . "Brus, Ji\u0159\u00ED" . . "Synthesis, structural study, and in vitro trypanocidal and antitumour activities of tetrakis(3-methoxypropyl)tin and (3-methoxypropyl)tin chlorides." . "630088" .