. . "RIV/61388980:_____/15:00442463" . "R\u016F\u017Ei\u010Dka, A." . "RIV/61388980:_____/15:00442463!RIV15-GA0-61388980" . "I, P(GAP207/11/0705)" . . "[63379CE48FB6]" . . "5"^^ . "34" . "Organometallics" . "2" . "000348619700007" . "10.1021/om500988z" . . . "Room-temperature reaction between nido-5,6-C2B8H12 (1) and elemental iodine in the presence of triethylamine in CH2Cl2 gave the closo-1,6-C2B8H10 (2) dicarbaborane in 85% yield. All the electrophilic halogenation reactions of 2 led exclusively to B(8)-substitution to get a series of 8-X-closo-1,6-C2B8H9 (8X-2) derivatives (where X = Cl, Br, and I). Thermal rearrangements of 2 and 8X-2 at similar to 500-600 degrees C produced closo-1,10-C2B8H10 (3) and a series of halo derivatives 2-X-closo-1,10-C2B8H9 (2X-3), respectively. All the compounds isolated have been characterized by multinuclear (B-11, H-1, and C-13) NMR spectroscopy, mass spectrometry, and elemental analyses, and the structure of 8Br-2 was established by X-ray diffraction study."@en . "Simple Synthesis, Halogenation, and Rearrangement of closo-1,6-C2B8H10"@en . . . . . "Pad\u011Blkov\u00E1, Z." . "3"^^ . "Room-temperature reaction between nido-5,6-C2B8H12 (1) and elemental iodine in the presence of triethylamine in CH2Cl2 gave the closo-1,6-C2B8H10 (2) dicarbaborane in 85% yield. All the electrophilic halogenation reactions of 2 led exclusively to B(8)-substitution to get a series of 8-X-closo-1,6-C2B8H9 (8X-2) derivatives (where X = Cl, Br, and I). Thermal rearrangements of 2 and 8X-2 at similar to 500-600 degrees C produced closo-1,10-C2B8H10 (3) and a series of halo derivatives 2-X-closo-1,10-C2B8H9 (2X-3), respectively. All the compounds isolated have been characterized by multinuclear (B-11, H-1, and C-13) NMR spectroscopy, mass spectrometry, and elemental analyses, and the structure of 8Br-2 was established by X-ray diffraction study." . "Simple Synthesis, Halogenation, and Rearrangement of closo-1,6-C2B8H10" . . "424" . "Simple Synthesis, Halogenation, and Rearrangement of closo-1,6-C2B8H10"@en . . . "\u0160t\u00EDbr, Bohumil" . "Simple Synthesis, Halogenation, and Rearrangement of closo-1,6-C2B8H10" . "Bakardjiev, Mario" . "Holub, Josef" . . "0276-7333" . "MAGNETIC-RESONANCE-SPECTROSCOPY; ORGANOELEMENTAL DERIVATIVES; CLOSO-BORANES; CARBORANES; 5,6-DICARBA-NIDO-DECABORANE(12)"@en . "US - Spojen\u00E9 st\u00E1ty americk\u00E9" . . . . . . . "5"^^ . .