. "boron; metallacarborane; ruthenium; tricarbollide"@en . "Cyclopentadienyl ruthenium comlexes with tricarbolide ligands"@en . . . . . . "Holub, Josef" . . "252607" . "Trifonova, E. A." . "0010-0765" . "Cyclopentadienyl ruthenium comlexes with tricarbolide ligands" . . "Cyclopentadienyl ruthenium comlexes with tricarbolide ligands"@en . "Kudinov, A. R." . "10"^^ . "000284230500006" . . . "[4DB054A24A4E]" . . . "Collection of Czechoslovak Chemical Communications" . . . . "75" . "Cyclopentadienyl ruthenium comlexes with tricarbolide ligands" . "5"^^ . . . "Reaction of the tricarbollide anion [7,8,9-C3B8H11](-) (1a) with the naphthalene complex [CpRu(C10H8)](+) under visible light irradiation in CH2Cl2 gives the 12-vertex closo-rthenacarborane 1-Cp-1,2,3,5-RuC3B8H11 (2; 87% yield). This complex was also obtained by reaction of 1a with CpRu(cod) Cl (97%). Upon heating at 80 C in toluene 2 rearranges into isomer 1-Cp-1,2,4,10-RuC3B8H11 (3; 63%). Irradiation of 1a with [CpRu(C10H8)](+) in acetone gives the 11-vertex closo-1-Cp-1,2,3,4-RuC3B7H10 (4; 32%). The latter was also prepared by reaction of 1a with [CpRu(MeCN)(3)]+ (59%). Compound 2 slowly undergoes cage contraction in acetone giving 4."@en . "CZ - \u010Cesk\u00E1 republika" . "Glukhov, I. V." . "P(LC523), Z(AV0Z40320502)" . "Reaction of the tricarbollide anion [7,8,9-C3B8H11](-) (1a) with the naphthalene complex [CpRu(C10H8)](+) under visible light irradiation in CH2Cl2 gives the 12-vertex closo-rthenacarborane 1-Cp-1,2,3,5-RuC3B8H11 (2; 87% yield). This complex was also obtained by reaction of 1a with CpRu(cod) Cl (97%). Upon heating at 80 C in toluene 2 rearranges into isomer 1-Cp-1,2,4,10-RuC3B8H11 (3; 63%). Irradiation of 1a with [CpRu(C10H8)](+) in acetone gives the 11-vertex closo-1-Cp-1,2,3,4-RuC3B7H10 (4; 32%). The latter was also prepared by reaction of 1a with [CpRu(MeCN)(3)]+ (59%). Compound 2 slowly undergoes cage contraction in acetone giving 4." . . "11" . "RIV/61388980:_____/10:00354532!RIV11-MSM-61388980" . "Perekalin, D. S." . "RIV/61388980:_____/10:00354532" . "1"^^ .