. "Macropolyhedral boron-containing cluster chemistry. Ligand-induced two-electron variations of intercluster bonding intimacy. Structures of nineteen-vertex[(eta(5)-C5Me5) HIrB18H19(PMe2Ph)] and the related carbene complex [(eta(5)-C5Me5)HIrB18H19{C(NHM..." . "GB - Spojen\u00E9 kr\u00E1lovstv\u00ED Velk\u00E9 Brit\u00E1nie a Severn\u00EDho Irska" . "Makropolyedrick\u00E1 borov\u00E1 chemie. Dvouelektronov\u00E9 variace intraklastrov\u00E9 vazebn\u00E9 intimity indukovan\u00E9 ligandem.. Struktury 19-vrcholov\u00E9ho ... a podobn\u00E9ho karbenov\u00E9ho komplexu"@cs . "3"^^ . "10" . "Pops\u00E1na je p\u0159\u00EDprava a genese dvou nov\u00FDch slou\u010Denin v 19-vrcholov\u00E9 iridaboranov\u00E9 \u0159ad\u011B."@cs . "Addition of PMe2Ph to fused-cluster syn-[(eta(5)-C5Me5)IrB18H20] 1 to give [(eta(5)-C5Me5) HIrB18H19(PMe2Ph)] 3 entails a diminution in the degree of intimacy of the intercluster fusion, rather than retention of inter-subcluster binding intimacy and a nido --> arachno conversion of the character of either of the subclusters. Reaction with MeNC gives [(eta(5)-C5Me5) HIrB18H19{C(NHMe)(2)}] 4 which has a similar structure, but with the ligand now being the carbene {: C(NHMe)(2)}, resulting from a reductive assembly reaction involving two MeNC residues and the loss of a carbon atom." . . . "-" . . . "Kennedy, J. D." . . . "Perera, S. D." . "6"^^ . "P(IAA4032701), Z(AV0Z4032918)" . "Macropolyhedral boron-containing cluster chemistry. Ligand-induced two-electron variations of intercluster bonding intimacy. Structures of nineteen-vertex[(eta(5)-C5Me5) HIrB18H19(PMe2Ph)] and the related carbene complex [(eta(5)-C5Me5)HIrB18H19{C(NHM..."@en . "RIV/61388980:_____/04:00108166!RIV/2005/AV0/A50005/N" . "1477-9226" . "2"^^ . "Macropolyhedral boron-containing cluster chemistry. Ligand-induced two-electron variations of intercluster bonding intimacy. Structures of nineteen-vertex[(eta(5)-C5Me5) HIrB18H19(PMe2Ph)] and the related carbene complex [(eta(5)-C5Me5)HIrB18H19{C(NHM..."@en . "RIV/61388980:_____/04:00108166" . . "Macropolyhedral boron-containing cluster chemistry. Ligand-induced two-electron variations of intercluster bonding intimacy. Structures of nineteen-vertex[(eta(5)-C5Me5) HIrB18H19(PMe2Ph)] and the related carbene complex [(eta(5)-C5Me5)HIrB18H19{C(NHM..." . "Makropolyedrick\u00E1 borov\u00E1 chemie. Dvouelektronov\u00E9 variace intraklastrov\u00E9 vazebn\u00E9 intimity indukovan\u00E9 ligandem.. Struktury 19-vrcholov\u00E9ho ... a podobn\u00E9ho karbenov\u00E9ho komplexu"@cs . "571975" . . . . . "Addition of PMe2Ph to fused-cluster syn-[(eta(5)-C5Me5)IrB18H20] 1 to give [(eta(5)-C5Me5) HIrB18H19(PMe2Ph)] 3 entails a diminution in the degree of intimacy of the intercluster fusion, rather than retention of inter-subcluster binding intimacy and a nido --> arachno conversion of the character of either of the subclusters. Reaction with MeNC gives [(eta(5)-C5Me5) HIrB18H19{C(NHMe)(2)}] 4 which has a similar structure, but with the ligand now being the carbene {: C(NHMe)(2)}, resulting from a reductive assembly reaction involving two MeNC residues and the loss of a carbon atom."@en . . "Jel\u00EDnek, Tom\u00E1\u0161" . "Dalton Transactions" . . . "[18595B3EF07C]" . "carboranes; 19-vertex; boranes"@en . "1521;1523" . . . "Shea, S. L." . "\u0160t\u00EDbr, Bohumil" . . "Thornton-Pett, M." .