. "RIV/61388980:_____/04:00106529!RIV/2005/AV0/A50005/N" . "Metallakarbor\u00E1nov\u00E1 chemie aniontu hypho-[6,7-C2B6H13](-) : p\u0159\u00EDprava nov\u00FDch metallakarbor\u00E1n\u016F s jedine\u010Dn\u00FDmi strukturami [5-Cp*-arachno-5,4,6-RhC2B6H12] a [2,5-(Cp*)2-10-Me-nido-2,5,1-Rh2CB6H9 : \u00FApln\u00E1 rhodiov\u00E1 analoga arachno-4,6-C2B7H13 a nido-1-CB8H12"@cs . "0022-328X" . . "Metallacarborane chemistry of the hypho-[6,7-C2B6H13](-)1-anion: the formation of uniquely structured metallacarboranes [5-Cp*-arachno-5,4,6-RhC2B6H12] and [2,5-Cp-2(*)-10-Me-nido-2,5,1-Rh2CB6H9] (Cp-* = eta(5)-C5Me5-): complete rhodium analogues of a..."@en . "689" . "16" . "RIV/61388980:_____/04:00106529" . . "2702;2706" . . "Metallacarborane chemistry of the hypho-[6,7-C2B6H13](-)1-anion: the formation of uniquely structured metallacarboranes [5-Cp*-arachno-5,4,6-RhC2B6H12] and [2,5-Cp-2(*)-10-Me-nido-2,5,1-Rh2CB6H9] (Cp-* = eta(5)-C5Me5-): complete rhodium analogues of a..."@en . "[677B3192D6B2]" . "Reaction of the tetramethyl ammonium salt of the hypho-[6,7-C2B6H13](-) anion (1) with the [Rh(eta(5)-C5Me5)Cl-2](2) dimer in THF solution, resulted in the formation of a novel nine-vertex metalladicarbaborane [5-Cp*-arachno-5,4,6-RhC2B6H12](2) (Cp* = eta(5)-C5Me5). An analogous reaction, but in the presence of PS (PS='proton-sponge'=1,8-bis-(dimethylamino)-naphthalene), resulted in the bimetallic nine-vertex species [2,5-Cp*(2)-10-Me-nido-2,5,1-Rh2CB6H9] (3). Compounds 2 and 3 are structural analogues of carboranes arachno-4,6-C2B7H13 (4) and nido-1-CB8H12 (5), respectively. The formation of compound 3 is associated with an extrusion of one of the cluster carbon atoms into an exo-polyhedral position and exhibits a very rare nine-vertex nido metallaborane structure with interesting features. Both species 2 and 3 were characterized by multinuclear NMR measurements and single-crystal X-ray diffraction studies." . . "C\u00EDsa\u0159ov\u00E1, I." . . . "P(LN00A028), Z(AV0Z4032918)" . . "boranes; metallacarboranes; rhodium complex"@en . "Metallakarbor\u00E1nov\u00E1 chemie aniontu hypho-[6,7-C2B6H13](-) : p\u0159\u00EDprava nov\u00FDch metallakarbor\u00E1n\u016F s jedine\u010Dn\u00FDmi strukturami [5-Cp*-arachno-5,4,6-RhC2B6H12] a [2,5-(Cp*)2-10-Me-nido-2,5,1-Rh2CB6H9 : \u00FApln\u00E1 rhodiov\u00E1 analoga arachno-4,6-C2B7H13 a nido-1-CB8H12"@cs . . "Londesborough, Michael Geoffrey Stephen" . "5"^^ . . "3"^^ . . "Metallacarborane chemistry of the hypho-[6,7-C2B6H13](-)1-anion: the formation of uniquely structured metallacarboranes [5-Cp*-arachno-5,4,6-RhC2B6H12] and [2,5-Cp-2(*)-10-Me-nido-2,5,1-Rh2CB6H9] (Cp-* = eta(5)-C5Me5-): complete rhodium analogues of a..." . . "\u0160t\u00EDbr, Bohumil" . "573048" . . "\u010Cl\u00E1nek popisuje tvorbu matallokarboran\u016F uveden\u00FDch v titulu \u010Dl\u00E1nku spole\u010Dn\u011B s popisem metallokarboranu nesouc\u00EDho m\u00E1lo se vyskytuj\u00EDc\u00ED Rh-H-Rh m\u016Fstkov\u00FD vodikov\u00FD atom."@cs . . . "CH - \u0160v\u00FDcarsk\u00E1 konfederace" . "Janou\u0161ek, Zbyn\u011Bk" . "Journal of Organometalic Chemistry" . "Londesborough, Michael Geoffrey Stephen" . "4"^^ . . "Metallacarborane chemistry of the hypho-[6,7-C2B6H13](-)1-anion: the formation of uniquely structured metallacarboranes [5-Cp*-arachno-5,4,6-RhC2B6H12] and [2,5-Cp-2(*)-10-Me-nido-2,5,1-Rh2CB6H9] (Cp-* = eta(5)-C5Me5-): complete rhodium analogues of a..." . "Reaction of the tetramethyl ammonium salt of the hypho-[6,7-C2B6H13](-) anion (1) with the [Rh(eta(5)-C5Me5)Cl-2](2) dimer in THF solution, resulted in the formation of a novel nine-vertex metalladicarbaborane [5-Cp*-arachno-5,4,6-RhC2B6H12](2) (Cp* = eta(5)-C5Me5). An analogous reaction, but in the presence of PS (PS='proton-sponge'=1,8-bis-(dimethylamino)-naphthalene), resulted in the bimetallic nine-vertex species [2,5-Cp*(2)-10-Me-nido-2,5,1-Rh2CB6H9] (3). Compounds 2 and 3 are structural analogues of carboranes arachno-4,6-C2B7H13 (4) and nido-1-CB8H12 (5), respectively. The formation of compound 3 is associated with an extrusion of one of the cluster carbon atoms into an exo-polyhedral position and exhibits a very rare nine-vertex nido metallaborane structure with interesting features. Both species 2 and 3 were characterized by multinuclear NMR measurements and single-crystal X-ray diffraction studies."@en . . .