"13" . "Thermal isomerisation of the ferraphosphadicarbaborane [1-Cp-closo-1,2,4,5-FePC2B8H10] (1a; Cp = eta(5)-C5H5-) at elevated temperatures (180-350 degreesC) leads to the formation of three new isomeric complexes. These were characterized by multinuclear (H-1, B-11, P-31, and C-13) NMR spectroscopy and mass spectrometry as [1-Cp-closo-1,2,3,8-FePC2B8H10] (1b), [1-Cp-closo-1,10,2,4-FePC2B8H10] (1c), and closo-[1,2,4,10-FePC2B8H10] (1d). The formation of lb is accompanied by an unusual agglomeration of the P and C heteroatoms. Complexes 1b and 1c have also been isolated as side products from the direct reaction between nido-[7,8,9-PC2B8H11] (2) and [CpFe(CO)(2)](2) in refluxing mesitylene, and 1a and 1b from the pyrolysis of [7-Fp-(eta(1)-nido-7,9,10-PC2B8H10)] [3; Fp = CpFe(CO)(2)] at 350 degreesC. NMR intercomparisons of all five [1-Cp-closo-FePC2B8H10] isomers thus far isolated have been made." . . . "5"^^ . "Phosphadicarbaborane analogues of ferrocene: New isomers of [closo-(eta(5)-C5H5)FePC2B8H10]." . "P(LN00A028), Z(AV0Z4032918)" . "Tok, O. L." . "Phosphadicarbaborane analogues of ferrocene: New isomers of [closo-(eta(5)-C5H5)FePC2B8H10]."@en . . . "N/A" . "Phosphadicarbaborane analogues of ferrocene: New isomers of [closo-(eta(5)-C5H5)FePC2B8H10]."@en . "European Journal of Inorganic Chemistry" . . . . "Bakardjiev, Mario" . "Thermal isomerisation of the ferraphosphadicarbaborane [1-Cp-closo-1,2,4,5-FePC2B8H10] (1a; Cp = eta(5)-C5H5-) at elevated temperatures (180-350 degreesC) leads to the formation of three new isomeric complexes. These were characterized by multinuclear (H-1, B-11, P-31, and C-13) NMR spectroscopy and mass spectrometry as [1-Cp-closo-1,2,3,8-FePC2B8H10] (1b), [1-Cp-closo-1,10,2,4-FePC2B8H10] (1c), and closo-[1,2,4,10-FePC2B8H10] (1d). The formation of lb is accompanied by an unusual agglomeration of the P and C heteroatoms. Complexes 1b and 1c have also been isolated as side products from the direct reaction between nido-[7,8,9-PC2B8H11] (2) and [CpFe(CO)(2)](2) in refluxing mesitylene, and 1a and 1b from the pyrolysis of [7-Fp-(eta(1)-nido-7,9,10-PC2B8H10)] [3; Fp = CpFe(CO)(2)] at 350 degreesC. NMR intercomparisons of all five [1-Cp-closo-FePC2B8H10] isomers thus far isolated have been made."@en . . . "RIV/61388980:_____/03:50033013!RIV/2004/MSM/A50004/N" . "Holub, Josef" . . "1434-1948" . . "0"^^ . "[FE6CE7D672EF]" . "0"^^ . "3"^^ . "Phosphadicarbaborane analogues of ferrocene: New isomers of [closo-(eta(5)-C5H5)FePC2B8H10]." . "620797" . . . . "DE - Spolkov\u00E1 republika N\u011Bmecko" . . "2524;2528" . . . "sandwich complexes; boranes; isomerisation"@en . "6"^^ . . "Wrackmeyer, B." . . "\u0160t\u00EDbr, Bohumil" . "RIV/61388980:_____/03:50033013" . "Pavl\u00EDk, I." .